Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2Tyndall, John
Science
Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2
Tyndall, John
Chemistry; Physics; Science
By a puff of tobacco-smoke, or of condensed steam, blown into the
illuminated beam, the brilliancy of the selenite colours may be
greatly enhanced. But with different clouds two different effects are
produced. Let the ring-system observed in the common air be brought
to its maximum strength, and then let an attenuated cloud of chloride
of ammonium be thrown into the beam at the point looked at; the ring
system flashes out with augmented brilliancy, but the character of the
polarisation remains unchanged. This is also the case when
phosphorus, or sulphur, is burned underneath the beam, so as to cause
the fine particles of phosphorus or of sulphur to rise into the light.
With the sulphur-fumes the brilliancy of the colours is exceedingly
intensified; but in none of these cases is there any change in the
character of the polarisation.
But when a puff of the fumes of hydrochloric acid, hydriodic acid, or
nitric acid is thrown into the beam, there is a complete reversal of
the selenite tints. Each of these clouds twists the plane of
polarisation 90°, causing the centre of the ring-system to change from
black to white, and the rings themselves to emit their complementary
colours. [Footnote: Sir John Herschel suggested to me that this
change of the polarisation from positive to negative may indicate a
change from polarisation by reflection to polarisation by refraction.
This thought repeatedly occurred to me while looking at the effects;
but it will require much following up before it emerges into
clearness.]
Almost all liquids have motes in them sufficiently numerous to
polarise sensibly the light, and very beautiful effects may be
obtained by simple artificial devices. When, for example, a cell of
distilled water is placed in front of the electric lamp, and a thin
slice of the beam is permitted to pass through it, scarcely any
polarised light is discharged, and scarcely any colour produced with a
plate of selenite. But if a bit of soap be agitated in the water above
the beam, the moment the infinitesimal particles reach the light the
liquid sends forth laterally almost perfectly polarised light; and if
the selenite be employed, vivid colours flash into existence. A still
more brilliant result is obtained with mastic dissolved in a great
excess of alcohol.
The selenite rings, in fact, constitute an extremely delicate test as
to the collective quantity of individually invisible particles in a
liquid. Commencing with distilled water, for example, a thick slice
of light is necessary to make the polarisation of its suspended
particles sensible. A much thinner slice suffices for common water;
while, with Bruecke's precipitated mastic, a slice too thin to produce
any sensible effect with most other liquids, suffices to bring out
vividly the selenite colours.
3. THE SKY OF THE ALPS.
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