Gem-Stones and Their Distinctive CharactersSmith, George Frederick Herbert
Science
Gem-Stones and Their Distinctive Characters
Smith, George Frederick Herbert
Precious stones
Considered from the scientific point of view, zircon is by far the most
interesting and the most remarkable of the gem-stones. The problem
presented by its characters and constitution is one that still awaits
a satisfactory solution. Certain zircons, which are found as rolled
pebbles in Ceylon and never show any trace of crystalline faces, have
very nearly single refraction, and the values of the refractive index
vary from 1·790 to 1·840, and the specific gravity is about 4·00 to
4·14, and the hardness is slightly greater than that of quartz, being
about 7¼. On the other hand, such stones as the red zircons from
Expailly have remarkably different properties. They show crystalline
faces with tetragonal symmetry, the faces present being four prismatic
faces mutually intersecting at right angles and four inclined faces at
each end (Fig. 78). They have large double refraction, varying from
0·044 to 0·062, which is readily discerned in a cut stone (cf. p.
41), and the refractive indices are high, the ordinary index varying
from 1·923 to 1·931 and the extraordinary from 1·967 to 1·993. Since
the ordinary is less than the extraordinary index the sign of the
double refraction is positive. The specific gravity likewise is much
higher, varying from 4·67 to 4·71. The second type, therefore, sinks
in molten silver-thallium nitrate, whereas the first type floats. The
second type is also slightly harder, being about 7½ on Mohs’s scale.
By heating either of these types the physical characters are not much
altered, except that the colour is weakened or entirely driven off and
some change takes place in the double refraction. But between these
two types may be found zircons upon which the effect of heating is
striking. They seem to contract in size so that the specific gravity
increases as much as three units in the first place of decimals, and a
corresponding increase takes place in the refractive indices, and in
the amount of double refraction. The cause of these changes remains a
matter of speculation. Evidently a third type of zircon exists which
is capable of most intimate association with either of the other
types, and which is very susceptible to the effect of heat. It may be
noted that stones of the intermediate type are usually characterized
by a banded or zonal structure suggesting a want of homogeneity. The
theory has been advanced that zircon contains an unknown element which
has not yet been separated from zirconium. Zircon of the first type
favours green, sky-blue, and golden-yellow colours; honey-yellow, light
green, blue, and red colours characterize the second type; and the
intermediate stones are mostly yellowish green, cloudy blue, and green.
It is another peculiarity of zircon that it sometimes shows in the
spectroscope absorption bands (p. 61), which were observed in 1866 by
Church. Many zircons do not exhibit the bands at all, and others only
display the two prominent bands in the red end of the spectrum.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account