Dr. Carpenter has kindly examined under the microscope, sliced and polished specimens of these concretions, and of the solid marl-rock, collected in various places between the Colorado and Santa Fe Bajada. In the greater number, Dr. Carpenter finds that the whole substance presents a tolerably uniform amorphous character, but with traces of incipient crystalline metamorphosis; in other specimens he finds microscopically minute rounded concretions of an amorphous substance (resembling in size those in oolitic rocks, but not having a concentric structure), united by a cement which is often crystalline. In some, Dr. Carpenter can perceive distinct traces of shells, corals, Polythalamia, and rarely of spongoid bodies. For the sake of comparison, I sent Dr. Carpenter specimens of the calcareous rock, formed chiefly of fragments of recent shells, from Coquimbo in Chile: in one of these specimens, Dr. Carpenter finds, besides the larger fragments, microscopical particles of shells, and a varying quantity of opaque amorphous matter; in another specimen from the same bed, he finds the whole composed of the amorphous matter, with layers showing indications of an incipient crystalline metamorphosis: hence these latter specimens, both in external appearance and in microscopical structure, closely resemble those of the Pampas. Dr. Carpenter informs me that it is well known that chemical precipitation throws down carbonate of lime in the opaque amorphous state; and he is inclined to believe that the long-continued attrition of a calcareous body in a state of crystalline or semi-crystalline aggregation (as, for instance, in the ordinary shells of Mollusca, which, when sliced, are transparent) may yield the same result. From the intimate relations between all the Coquimbo specimens, I can hardly doubt that the amorphous carbonate of lime in them has resulted from the attrition and decay of the larger fragments of shell: whether the amorphous matter in the marly rocks of the Pampas has likewise thus originated, it would be hazardous to conjecture. For convenience’ sake, I will call the marly rock by the name given to it by the inhabitants, namely, Tosca-rock; and the reddish argillaceous earth, Pampean mud. This latter substance, I may mention, has been examined for me by Professor Ehrenberg, and the result of his examination will be given under the proper localities.