Between these points and Mercedes on the Rio Negro, there are scarcely any good sections, the road passing over limestone, tosca-rock, calcareous and bright red sandstones, and near the source of the San Salvador over a wide extent of jaspery rocks, with much milky agate, like that in the limestone near San Juan. In the estancia of Berquelo, the separate, flat-topped, cliff-bounded hills are rather higher than in the other parts of the country; they range in a N.E. and S.W. direction; their uppermost beds consist of the same bright red sandstone, passing sometimes into a conglomerate, and in the lower part into soft white sandstone, and even into loose sand: beneath this sandstone, I saw in two places layers of calcareous and marly rocks, and in one place red Pampean-like earth; at the base of these sections, there was a hard, stratified, white sandstone, with chalcedonic layers. Near Mercedes, beds of the same nature and apparently of the same age, are associated with compact, white, crystalline limestone, including much botryoidal agate, and singular masses, like porcelain, but really composed of a calcareo-siliceous paste. In sinking wells in this district the chalcedonic strata seem to be the lowest. Beds, such as there described, occur over the whole of this neighbourhood; but twenty miles further up the R. Negro, in the cliffs of Perika, which are about fifty feet in height, the upper bed is a prettily variegated chalcedony, mingled with a pure white tallowy limestone; beneath this there is a conglomerate of quartz and granite; beneath this many sandstones, some highly calcareous; and the whole lower two-thirds of the cliff consists of earthy calcareous beds of various degrees of purity, with one layer of reddish Pampean-like mud. When examining the agates, the chalcedonic and jaspery rocks, some of the limestones, and even the bright red sandstones, I was forcibly struck with their resemblance to deposits formed in the neighbourhood of volcanic action. I now find that M. Isabelle, in his “Voyage a Buenos Ayres,” has described closely similar beds on Itaquy and Ibicuy (which enter the Uruguay some way north of the R. Negro) and these beds include fragments of red decomposed true scoriae hardened by zeolite, and of black retinite: we have then here good evidence of volcanic action during our tertiary period. Still further north, near S. Anna, where the Parana makes a remarkable bend, M. Bonpland found some singular amygdaloidal rocks, which perhaps may belong to this same epoch. (M. d’Orbigny “Voyage” Part. Geolog. page 29) I may remark that, judging from the size and well-rounded condition of the blocks of rock in the above-described conglomerates, masses of primary formation probably existed at this tertiary period above water: there is, also, according to M. Isabelle, much conglomerate further north, at Salto.