the Cachapual, I found columnar pitchstone porphyritic with feldspar; I do not suppose this rock to be of volcanic origin, and only mention it here, from its being intersected by masses and dikes of a VESICULAR rock, approaching in character to trachyte; in no other part of Chile did I observe vesicular or amygdaloidal dikes, though these are so common in ordinary volcanic districts. PASSAGE OF THE ANDES BY THE PORTILLO OR PEQUENES PASS. Although I crossed the Cordillera only once by this pass, and only once by that of the Cumbre or Uspallata (presently to be described), riding slowly and halting occasionally to ascend the mountains, there are many circumstances favourable to obtaining a more faithful sketch of their structure than would at first be thought possible from so short an examination. The mountains are steep and absolutely bare of vegetation; the atmosphere is resplendently clear; the stratification distinct; and the rocks brightly and variously coloured: some of the natural sections might be truly compared for distinctness to those coloured ones in geological works. Considering how little is known of the structure of this gigantic range, to which I particularly attended, most travellers having collected only specimens of the rocks, I think my sketch-sections, though necessarily imperfect, possess some interest. Section 1/1 in Plate 1 which I will now describe in detail, is on a horizontal scale of a third of an inch to a nautical mile, and on a vertical scale of one inch to a mile (or 6,000 feet). The width of the range (excluding a few outlying hillocks), from the plain on which St. Jago the capital of Chile stands, to the Pampas, is sixty miles, as far as I can judge from the maps, which differ from each other and are all EXCEEDINGLY imperfect. The St. Jago plain at the mouth of the Maypu, I estimate from adjoining known points at 2,300 feet, and the Pampas at 3,500 feet, both above the level of the sea. The height of the Pequenes line, according to Dr. Gillies, is 13,210 feet (“Journal of Natural and Geographical Science” August 1830.); and that of the Portillo line (both in the gaps where the road crosses them) is 14,345 feet; the lowest part of the intermediate valley of Tenuyan is 7,530 feet—all above the level of the sea.