The altered clay-slate formation, already described, is seen in several parts of the valley as far down as Las Vacas, underlying the porphyritic conglomerate. At the Casa de Pujios [L], there is a hummock of (andesitic?) granite; and the stratification of the surrounding mountains here changes from W. by S. to S.W. Again, near the R. Vacas there is a larger formation of (andesitic?) granite [M], which sends a meshwork of veins into the superincumbent clay-slate, and which locally throws off the strata, on one side to N.W. and on the other to S.E. but not at a high angle: at the junction, the clay-slate is altered into fine-grained greenstone. This granitic axis is intersected by a green dike, which I mention, because I do not remember having elsewhere seen dikes in this lowest and latest intrusive rock. From the R. Vacas to the plain of Uspallata, the valley runs N.E., so that I have had to contract my section; it runs exclusively through porphyritic rocks. As far as the Pass of Jaula, the claystone conglomerate formation, in most parts highly porphyritic, and crossed by numerous dikes of greenstone porphyry, attains a great thickness: there is also much intrusive porphyry. From the Jaula to the plain, the stratification has been in most places obliterated, except near the tops of some of the mountains; and the metamorphic action has been extremely great. In this space, the number and bulk of the intrusive masses of differently coloured porphyries, injected one into another and intersected by dikes, is truly extraordinary. I saw one mountain of whitish porphyry, from which two huge dikes, thinning out, branched DOWNWARDS into an adjoining blackish porphyry. Another hill of white porphyry, which had burst through dark- coloured strata, was itself injected by a purple, brecciated, and recemented porphyry, both being crossed by a green dike, and both having been upheaved and injected by a granitic dome. One brick-red porphyry, which above the Jaula forms an isolated mass in the midst of the porphyritic conglomerate formation, and lower down the valley a magnificent group of peaked mountains, differs remarkably from all the other porphyries. It consists of a red feldspathic base, including some rather large crystals of red feldspar, numerous large angular grains of quartz, and little bits of a soft green mineral answering in most of its characters to soapstone. The crystals of red feldspar resemble in external appearance those of orthite, though, from being partially decomposed, I was unable to measure them; and they certainly are quite unlike the variety, so abundantly met with in almost all the other rocks of this line of section, and which, wherever I tried it, cleaved like albite. This brick-red porphyry appears to have burst through all the other porphyries, and numerous red dikes traversing the neighbouring mountains have proceeded from it: in some few places, however, it was intersected by white dikes. From this