The road by the Villa Vicencio Pass does not strike directly across the range, but runs for some leagues northward along its western base: and I must briefly describe the rocks here seen, before continuing with the coloured east and west section. At the mouth of the valley of Canota, and at several points northwards, there is an extensive formation of a glossy and harsh, and of a feldspathic clay-slate, including strata of grauwacke, and having a tortuous, nearly vertical cleavage, traversed by numerous metalliferous veins and others of quartz. The clay-slate is in many parts capped by a thick mass of fragments of the same rock, firmly recemented; and both together have been injected and broken up by very numerous hillocks, ranging north and south, of lilac, white, dark and salmon- coloured porphyries: one steep, now denuded, hillock of porphyry had its face as distinctly impressed with the angles of a fragmentary mass of the slate, with some of the points still remaining embedded, as sealing-wax could be by a seal. At the mouth of this same valley of Canota, in a fine escarpment having the strata dipping from 50 to 60 degrees to the N.E. (Nearly opposite to this escarpment, there is another corresponding one, with the strata dipping not to the exactly opposite point, or S.W., but to S.S.W.: consequently the two escarpments trend towards each other, and some miles southward they become actually united: this is a form of elevation which I have not elsewhere seen.), the clay-slate formation is seen to be covered by—(1st) a purple, claystone porphyry resting unconformably in some parts on the solid slate, and in others on a thick fragmentary mass; (2nd), a conformable stratum of compact blackish rock, having a spheroidal structure, full of minute acicular crystals of glassy feldspar, with red spots of oxide of iron; (3rd), a great stratum of purplish-red claystone porphyry, abounding with crystals of opaque feldspar, and laminated with thin, parallel, often short, layers, and likewise with great irregular patches of white, earthy, semi-crystalline feldspar; this rock (which I noticed in other neighbouring places) perfectly resembles a curious variety described at Port Desire, and occasionally occurs in the great porphyritic conglomerate formation of Chile; (4th), a thin stratum of greenish white, indurated tuff, fusible and containing broken crystals and particles of porphyries; (5th), a grand mass, imperfectly columnar and divided into three parallel and closely joined strata, of cream-coloured claystone porphyry; (6th), a thick stratum of lilac-coloured porphyry, which I could see was capped by another bed of the cream-coloured variety; I was unable to examine the still higher parts of the escarpment. These conformably stratified porphyries, though none are either vesicular are amygdaloidal, have evidently flowed as submarine lavas: some of them are separated from each other by seams of indurated tuff, which, however, are quite insignificant in