The composition of the window-glass of the thirteenth century is in
some ways remarkable. It contained as much as from 8 to 10 per cent. of
alumina, which we must regard as replacing in a measure the silica, for
this constituent falls to as low as 56 per cent., and we can hardly
otherwise account for the high percentage of the other bases—14 per
cent. of lime, 17 per cent. of potash, and often 3 or 4 per cent. of
iron. The result was a tough, somewhat horny glass, hard to work in
consequence of the short duration of the viscous stage during the
cooling. This was one reason for the smallness of the gatherings, and
the modest dimensions of the resultant discs. On the other hand, such
glass resists the action of the atmosphere better than any made
nowadays, and the large amount of potash present probably promoted the
brilliancy of the colours. From the earliest times the blue colouring
was given by cobalt, and this was never of a richer and purer tint than
in the twelfth century; already in the thirteenth copper was added to
correct a tendency to purple. The famous ruby red, which became rarer
after the thirteenth century until in the seventeenth the secret was
entirely lost, was produced by the partial reduction of a small
quantity of suboxide of copper, but in this case the colour is only
developed on reheating the glass. The more purplish tint given by a
somewhat similar treatment with gold was not known to the mediæval
glass-maker.[95] Manganese was of course the source of the purple—the
colour was used for flesh-tints in the twelfth century! The green was
made by a mixture of the _æs ustum_ or copper scale with a native oxide
of iron, the latter often known as _ferretto_—of this the best came
from Spain. Finally, the yellow was given either by the sesqui-oxide of
iron kept well oxidised by the presence of bin-oxide of manganese, or
(where the surroundings favoured a reducing action) by a mixture of
sulphur and some sooty material which probably yielded an alkaline
sulphide. But in the older glass the yellow colour was never very
brilliant; at a later time a fine yellow was obtained by a cementation
process from silver, which was applied as a chloride or a sulphide to
the surface of the glass.
If I trespass beyond my limits to give this rapid summary of what is
known of the colours of mediæval window-glass, it is because much of it
will be found applicable to the contemporary Oriental enamelled ware
and to the later Venetian glass.
Public-domain text, read in full here on John Shaqi.
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