And here I may say that certain important technical difficulties, that
must always have hampered the use of true transparent enamels on glass,
have scarcely received the attention that they deserve. I mean the
relations of the enamels, as regards the softening-point and rate of
contraction on cooling, to the ground on which they rest. The question
here is very similar to that which presents itself in the case of
porcelain. Our present problem is, however, somewhat simpler, for with
the latter material we have not only to consider the relation of the
enamels to the glaze on which they lie (this takes, indeed, the place
of our glass ground), but in addition the relation of the glaze itself
to the porcelain body beneath must not be neglected.
The first condition for the successful application of an enamel is that
it should be more fusible than the glass to which it is applied; not
only that, but at the temperature at which the enamel fuses, the glass
must still maintain its rigidity, otherwise the vessel on coming from
the enameller’s stove will not preserve its original symmetry. It has
been already suggested that the partial collapse so often observed in
the large Cairene lamps may probably be explained in this way.
On the other hand, if the surface of the glass is not to some degree
softened, there will be no intimate connection between it and the
enamel, and the latter will be likely to scale off before long. This
tendency will be increased if there is much difference in the rate or
amount of contraction between the two materials. Difficulties of this
kind long hindered the employment of certain fluxes and colours—that
of cobalt, for instance, combined with a transparent flux. Such
obstacles may, however, be surmounted in a measure, and the process
simplified by employing (in place of a transparent lead flux) an opaque
white, stanniferous enamel merely stained, in cases only externally, by
a little colouring material. This apparently was the plan universally
adopted by the Venetians in the fifteenth century, and it is here that
their experience of the use of a similar enamel on copper may have
served them.
One cannot but marvel at the technical dexterity so early acquired,
and, alas! so soon lost by the Saracens, in the application of enamels
to glass. The means by which they avoided the use of a lead flux in the
case of their famous translucent blue, is above all worthy of
admiration (see above, Chapter X.).
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