The state in which the structure of glass exists when quickly cooled and
the action of annealing might be explained. When glass is quickly
cooled, being a bad conductor of heat, insufficient time is allowed for
the middle or interior portions of the glasswares to settle down and
assume their normal state of solidification. The outer portion, or
crust, will first cool and contract with an enormous strain upon the hot
interior. This difference in the state of tension between the outer and
interior portions gives a want of uniformity, and stresses of tension
and thrust are developed, which cause the whole to collapse with the
slightest external scratch or heat change. In annealing, this strained
or forced condition in the structure of the glass is relieved by
subjecting the glass to a pre-heating, and gradually diminishing the
temperature, allowing a sufficient time for the different layers
mutually to adjust themselves to their comparative normal positions, and
thus relieve the strains within the mass. Much depends upon the
pre-heating temperature and the rate at which the diminution of the
temperature takes place. If this is properly provided for, the best
results are obtained in the stability of the resulting glass. The
presence of any stress can be determined by using a polariscope.
The average British glass manufacturer has little knowledge of the value
of a polariscope, or stress viewer, in ascertaining the physical state
of his glasswares, and until he adopts its use there is little prospect
of an improvement in his annealing methods. Much faulty annealed glass
is being turned out which the glass manufacturer is not aware of, and
which could be avoided by the intelligent use of such a simple
instrument, which detects badly annealed glass at once by the aid of
crossed nicols and a selenite plate.
Owing to the unequal densities of the various silicates present in the
heavy lead and barium glasses, they are more subject to striation and
require more careful annealing than the soda-lime glasses, in which the
silicates present are of more equal density. However, much depends upon
the proper “founding” and melting of such glasses. The use of a larger
proportion of cullet assists in breaking up striation. The presence of
striae or cords in glass disqualifies it for most purposes, as it is
usually found that, apart from their defective appearance, they tend to
produce stresses within the glass.
Transparency, brilliancy, stability, and homogeneity are important
factors in producing perfect glassware, and the proper development of
these distinguishing properties requires considerable skill on the part
of the glass manufacturer, alike from a technical, physical, and
practical standpoint.
------------------------------------------------------------------------
CHAPTER XI
THE MANIPULATION OF GLASS
GLASS MAKERS’ TOOLS AND MACHINES
Public-domain text, read in full here on John Shaqi.
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