In quite a different class from the imitation gems made of cut
flint-glass are the artificial gems, which in nature and composition
are exact reproductions of natural gems, but which have been produced
by artificial processes. As far as the writer is aware these are
only found in any large numbers in the case of the ruby, but in that
case, at all events, it is said that the production of the artificial
crystals is at least as costly as the purchase of the natural stones.
There can, however, be very little doubt that as the processes of
fusion and crystallisation become better known and understood, and the
chemistry of silicate minerals is developed, the artificial production
of mineral crystals in, at all events, moderate sizes will become
increasingly possible; it is even to be hoped that their production
will be so far perfected as to place their really valuable properties
at the service of man.
_Chilled Glass._--In all the processes of glass manufacture described
in the present book, annealing has always played an important part. The
glass, after it has undergone its last treatment under the influence
of heat, is subjected to a gradual cooling process with the object of
freeing it from the internal strains which it would otherwise retain,
and which would, ordinarily, endanger its existence and interfere with
its use. It is, however, well known that surfaces of glass subjected
to such internal strains as result in a compressive stress on the
glass near the surface, are less liable to injury, and are apparently
stronger than when the glass is annealed and the stresses are removed.
On the other hand, glass surfaces under tension are extremely delicate
and fragile. In some respects, therefore, glass which has not been
annealed may appear to be stronger than the annealed product. The
well-known case of the Rupert’s drop is an example of this kind.
Rupert’s drops are produced by dropping molten glass into water; they
generally take the form of a more or less spherical body having a long
tail, tapering off into a thread, attached to it. Such a Rupert’s drop
may be struck with a heavy hammer, and will safely resist a blow that
would splinter a similar body made of annealed glass. If, however, the
surface be scratched, or the tip of the tail be broken off, the entire
“drop” breaks up, sometimes with a violent explosion, into minute
fragments. Numerous inventors, among whom De la Bastie and Siemens
figure most conspicuously, have endeavoured to utilise these properties
of chilled glass, not exactly by endeavouring to produce that extreme
degree of internal strain which is characteristic of the Rupert’s drop,
but by producing what they describe as “tempered” glass, in which the
internal strains have been reduced by less violent cooling to such an
extent as to retain some of the advantages of the hardened, internally
strained condition while approximating more or less to the safer state
of annealed glass.
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