We have now to consider the chemical reactions which take place in the
mixture of raw materials that are introduced into the hot furnace. The
exact course of these reactions is not known in very great detail, as
this could only be ascertained by an elaborate research on the nature
of the intermediate products that result under various circumstances.
A research of this kind would throw much light on the whole of the
melting processes but is in itself so difficult that it has not yet
been carried out at all fully. We can therefore only give an account of
the chemical changes from our knowledge of the end-results and of a few
intermediate products that are known. To take the simplest case, we may
consider a mixture consisting of sand, carbonate of lime and carbonate
of soda mixed in suitable proportions. In such a case we know that
the mere action of heat alone will produce two changes--the carbonate
of soda will melt and the carbonate of lime will lose its carbonic
acid and be “burnt” or converted into caustic lime. The first stage
of the fusion process thus probably results in a mass consisting of
sand grains and grains of carbonate of lime undergoing decomposition,
all cemented together by molten carbonate of soda. This mass will
be full of bubbles, some derived from the air enclosed between the
grains of the original mixture and thus trapped by the melting mass,
and others formed by the carbonic acid which is being driven off in
the form of gas by the decomposition of the carbonate of lime. At the
temperature of the furnace, however, silica has the properties of a
strong acid, and not only attacks the carbonate of lime much in the
same manner as, for instance, hydrochloric acid would do in the cold,
but the silica also attacks the carbonate of soda, which heat alone
can scarcely decompose. The exact order in which these reactions take
place will depend upon the temperature of the furnace and the degree
of mixing attained in the preparation of the raw materials. Although
in the long run the final result will probably be the same as regards
purely chemical constitution, much of the technical success of the
process must depend upon the exact sequence of the changes involved, as
this must govern the number and size of the bubbles that are formed in
the glass and the fluidity of the mass from which these bubbles have
to free themselves. In the present state of our knowledge, however,
we can only say that the final result is the complete expulsion of
all carbonic acid from the compounds present (although it may remain
entangled in the glass in the form of bubbles) and the formation of
silicates of both lime and soda which remain in the finished glass in a
state partly of mutual chemical combination, partly of mutual solution.
Public-domain text, read in full here on John Shaqi.
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