The description of the process of fusion just given applies, with
slight modifications, to the melting of ordinary flint-glass mixtures
as well as to lime glasses, with the one modification that the
carbonate of lime of the lime-soda glass is replaced by red-lead, and
the gas evolved by the decomposition of the red-lead is oxygen in place
of the carbonic acid evolved from the decomposition of the carbonate
of lime. In the case of both lime and flint glasses, however, certain
other substances besides those mentioned are usually introduced in
small quantities. Although these substances do not very materially
affect the end-products of the chemical reactions, they very materially
affect the intermediate stages, and thus serve the purpose for which
they are introduced by affecting the course of the chemical changes in
a favourable manner. The substances usually employed for this purpose
are arsenic and nitrate of either soda or potash. The manner in which
the arsenic acts is very obscure and cannot be discussed in detail
here; the chief factors in its action are, however, its volatility and
its power of either absorbing oxygen or parting with it according to
circumstances. The action of the nitrates is chiefly dependent upon
the oxygen which they yield on decomposition by heat. This oxygen is
in some cases stored up by other ingredients of the mixture and only
given off at a much later stage, when the evolution of this gas assists
in the removal of the last small bubbles of inert air or carbonic acid
gas still left in the glass. The oxidising action of the nitrates,
however, serves chiefly for the destruction of organic matter and
the full oxidation of any iron present; both processes which tend to
improve the colour of the glass, while in the case of flint glasses the
presence of these oxidising additions is necessary to avoid all risk of
reduction of lead, since this would result in the complete blackening
of the glass.
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