Having now briefly considered the process of fusion proper, we pass
to the second stage in the melting of glass. In a properly conducted
glass-furnace, when the last trace of undecomposed raw materials has
disappeared, we find the glass as a transparent mass throughout which
gas bubbles are thickly disseminated. For the majority of purposes it
is necessary to free the glass as perfectly as possible from these
bubbles before it is worked into its final form. This freeing or
“fining” process is carried out by further and more intense heating
of the molten glass, which is thereby rendered more fluid and allows
the bubbles to disengage themselves by rising to the surface. This
occurs much more readily when the bubbles are large; very minute
bubbles, in fact, show no inclination to rise through the fluid mass.
The glass-maker accordingly compounds his mixtures of raw materials in
such a way as to yield large bubbles, or, failing that, he adds to the
molten mass some substance that evolves a great many large bubbles, and
these in their upward course through the glass sweep the small ones
away with them. The added substance may be an inorganic volatile body,
such as arsenic, or more frequently some vegetable substance containing
much moisture is introduced into the glass. The most usual method is
to place a potato in the crook of a forked iron rod and then to dip
the rod with the attached potato into the molten glass; the heat at
once begins to drive off the moisture and to decompose the potato, so
that there is a violent ebullition of the whole mass. This “boiling
up” process assists the fining considerably and also serves to mix the
whole contents of the pot very thoroughly, but it has some attendant
disadvantages, such as the introduction of oxide of iron into the glass
from the rod which is used in the operation, while the contaminated
material adhering to the walls of the pot itself is dragged off and
mixed with the rest of the glass by the violent stirring action that
takes place. It is, of course, further obvious that this process can
only be usefully applied to glass melted in pots, since the bulk of
the molten glass in a tank furnace could not be reached at all in
this manner. Mixtures that are to be melted in tanks must therefore be
capable of freeing themselves of their enclosed bubbles without such
outside aid. In a tank, in fact, the whole melting process proceeds on
somewhat different lines, since the temperature of the furnace is never
intentionally varied, while on the other hand the melting glass travels
down the furnace into regions whose temperature can be regulated to
favour the various stages of the process that take place in each part
of the furnace. On the whole, however, it is an undoubted fact that
while the running of a pot furnace can be varied, within wide limits,
to suit the requirements of whatever mixture it is desired to melt, in
the case of tank furnaces the mixture must be closely adjusted to the
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