The electrotype, electro-gilding and plating, and the other applications of the deposition of metals from their solutions, by the agency of voltaic electricity, had their origin in the chance observation of peculiarities in frequently repeated experiments. In this, as in most other inventions, there are contending claimants for priority; but there is little merit due to any of the first discoverers of the process, who seem to have been guided altogether by accident. It seems strange, now, on observing the extensive use that is made of the deposition of metals, that it should have remained so long unapplied after the principle had been known. The "revivification," as it was called, of metals from their solutions by voltaic electricity, was known at the beginning of the present century; for, in 1805, Brugnatelli, an Italian chemist, gilded a silver medal by connecting it with the negative pole of a voltaic battery, when immersed in a solution of ammoniuret of gold. It did not occur to him, however, that any use could be made of that mode of gilding, and the experiment had no result. Nothing further was done, even experimentally, towards advancing the art of electrotyping, until Mr. Spencer, of Liverpool, when experimenting with a Daniell's battery, in 1837, accidentally coated a penny piece with copper; and when the thin sheet of metal was removed, he found on it an exact counterpart of the head and letters of the coin. Even this did not suggest any useful application; nor was it until, by a further accident, a drop of varnish fell on the copper of the negative pole, and showed that no deposition took place on the part so covered, that the idea occurred to him of turning the deposition of the copper to account. The method he adopted of doing so was to cover a copper plate with varnish or wax, and to etch a design through the covering. By then exposing the plate to the action of a solution of sulphate of copper, when in connection with the negative pole of a voltaic battery, the metal was deposited in the lines drawn through the varnish, and a design in relief was fixed to the copper. This slight advance in the art was not made known until it was announced, in 1839, that Professor Jacobi, of St. Petersburg, had made application of the same process. Mr. Spencer, indeed, was forestalled, even in this country, by Mr. Jordan, a printer, who published an account in the _Mechanics' Magazine_ for May, 1839, of a method of making copper casts by the deposition of copper from its solution. In the autumn of the same year, however, Mr. Spencer exhibited to the British Association several more perfect specimens of electrotyping, that showed the process might be rendered valuable; and from that time rapid progress was made in bringing it into practical operation in a variety of ways.