Great Facts: A Popular History and Description of the Most Remarkable Inventions During the Present CenturyBakewell, Frederick C. (Frederick Collier)
History
Great Facts: A Popular History and Description of the Most Remarkable Inventions During the Present Century
Bakewell, Frederick C. (Frederick Collier)
Inventions
Mr. Talbot's patent was sealed on the 8th of February, 1841. In his
specification, he claimed the use of gallic acid, and he succeeded
in enforcing his claim in a Court of Law, though it appeared that on
the 10th of April, 1839, photographs of objects taken in the solar
microscope in five minutes, by the Rev. J. B. Reade, were shown at
the London institution, which were described to have been produced by
an infusion of galls, and fixed with hyposulphite of soda. It must be
mentioned, however, to Mr. Talbot's honour, that on a representation to
him by the President of the Royal Society that the art of Photography
was impeded in its progress in this country by patent monopolies,
he generously made a present to the public of all his inventions
and discoveries, reserving to himself only the privilege of taking
portraits.
The transfer from one paper to another of the picture obtained in
the camera, and the comparative roughness of the surface of the
paper itself, prevent Calotypes from exhibiting that sharpness and
delicacy of definition which are so admirable in a Daguerreotype.
Several attempts were therefore made to obtain a more smooth surface
for the reception of the image; but without much success, until glass
was adopted for the purpose. To make that material available, it is
necessary to coat it with some substance that will absorb the sensitive
solution. In the first instance, the white of eggs was employed
with considerable success. Albumen has, however, been supplanted by
collodion--a solution of gun-cotton in ether--which is found to be
peculiarly suitable for the reception of the sensitive preparation of
silver.
In conducting the collodion process, the collodion is first iodised by
adding to it iodide of potassium and iodide of silver, dissolved in
alcohol. The iodised collodion is then poured over a plate of glass
that has been carefully cleaned, and is moved about horizontally
until a perfectly uniform film is spread over the surface, to which
it adheres firmly. The plate is afterwards dipped into a solution of
nitrate of silver, which renders it so highly sensitive to impressions
of light, that it will receive an image in less than a second. The
image is latent, until it is developed by pouring over the plate a
mixture of pyro-gallic acid in distilled water, acetic acid, and
nitrate of silver. The impression is fixed with hyposulphite of soda.
The pictures produced by the collodion process are negatives, which
serve admirably for transferring positive pictures on to sensitive
paper. But, if required, the negative picture can be readily changed
into a positive one, by converting the darkened silver into white
metallic silver, by a mixture of protosulphate of iron and pyro-gallic
acid. In a short time a white metallic image is obtained, which, when
relieved by a background of black velvet or black varnish, equals in
delicacy of finish the most beautiful Daguerreotypes.
Public-domain text, read in full here on John Shaqi.
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