Harper's Electricity Book for BoysAdams, Joseph H. (Joseph Henry)
Science
Harper's Electricity Book for Boys
Adams, Joseph H. (Joseph Henry)
Electricity -- Juvenile literature
The crude copper plate is to be the leading-in pole for the current,
while a thin sheet of pure copper, no thicker than tissue-paper, is
suspended from the opposite rod for the leading-out pole; or in place of
the thin sheet, some copper wires may be suspended from the rod. The
electrodes--that is, the copper plate and the thin sheet or wires--are
placed close together, so that the current may pass freely and not
cause internal resistance in the battery. The electric current, in its
passage from the crude copper plate to the pure copper sheet or wires,
decomposes the sulphate of copper solution and causes it to deposit its
metallic copper on the sheet or wires; and at the same time it takes
from the crude copper a like portion of metallic copper and converts it
into chemical copper. The electric current really takes the copper from
the solution and adds it to the pure copper sheet, while the remaining
constituents of the decomposed solution help themselves to some copper
from the crude plate. In this way the crude copper diminishes and the
pure copper sheet increases in size, the impurities as well as the salts
of other metals being precipitated to the bottom of the tank, or mingled
with the solution, which must be purified or replaced from time to time
by fresh solution. This is the process of copper-plating, and any metal
object may be properly cleansed and coated with copper by suspending it
in the bath and running the current through it.
When the refining process is employed, any metal will answer as a
depository for the copper, but as the intention is to produce a pure
copper plate which can be melted and cast into ingots, it is of course
necessary to have the original kathode of the same metal; otherwise an
impure mixture will be the result. If, for example, a piece of cast-iron
be used upon which to deposit the copper, then the iron will be enclosed
in a deposit of pure copper; in other words, the result will be a
heavily copper-plated piece of iron, and the smelting process will bring
about a fusion of the two metals. It is not necessary to have absolutely
pure copper for the anodes when copper-plating or electrotyping; but
the purer the copper the less the solution is fouled, and it will not
require replenishing so often.
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