Harper's Electricity Book for BoysAdams, Joseph H. (Joseph Henry)
Science
Harper's Electricity Book for Boys
Adams, Joseph H. (Joseph Henry)
Electricity -- Juvenile literature
In copper-plating this is easy to determine without any regard to wires,
because if the wires are misconnected there will be no deposit, and the
kathode will turn a dark color. If everything is all right a slight
rose-colored blush of copper will appear at once on the kathode. Too
little current will make the process a long and tedious one, while too
much current will deposit a brown mud on the kathode, which will have to
be washed off or removed and the article thoroughly cleansed before a
new action is allowed to take place.
With a series of cells it is an easy matter to properly govern the
current by cutting out some of the cells or by using resistance-coils
(see chapter vii. on Electrical Resistance).
Cells and batteries for electro-plating may be made or purchased, and
primary batteries should be used. The use of the secondary or
storage-battery is not necessary for plating purposes, since no great
volume of current is needed, and it can be generated in a battery of
cells while the work is going on.
One of the best primary batteries is the Benson cell, shown in
connection with the plating-bath, and also in Fig. 11. It consists of an
outer glass jar (G J), which contains a cylinder of amalgamated zinc (Z
+, or positive) covered with diluted sulphuric acid--one part acid to
three parts water. An inner porous cup (P C) contains concentrated
nitric acid, into which the carbon (C -, or negative) is plunged. The
liquid in the inner cup and glass cell should be at the same level.
[Illustration: FIG. 10
FIG. 11
FIG. 12
THE BENSON CELL PRIMARY BATTERY]
There is no polarizing in this cell, for the hydrogen liberated at the
zinc plate, in passing through the nitric acid on its way to the
carbon-pole, decomposes the nitric acid and is itself oxidized. A cell
with a glass jar six inches in diameter and eight inches high will
develop about two volts of electro-motive force; and as its internal
resistance is very low it will furnish a steady current for several
hours. Any number of these cells may be made and connected in series;
but when not in use it would be well to remove and wash the zincs. Any
bichromate battery will answer very well for plating, the Grenet being
an especially good one. A well-amalgamated zinc plate forms one pole,
and a pair of carbon plates, one on each side of the zinc and joined at
the top, make up the other pole. When not in use the entire plunge part
should be removed from the bichromate solution, rinsed off in water, and
laid across the top of the jar, ready for its next employment. The zinc
and carbons must be joined together so that they are well insulated, and
with no chance of the zinc coming into contact with the carbons. This
may be done with four pieces of hard-wood soaked in hot paraffine and
then locked together with stove-bolts and nuts, as shown at Fig. 12.
Holes must be made in the top corners of the carbons and zinc, and with
small bolts and nuts the connecting wires can be made fast.
Public-domain text, read in full here on John Shaqi.
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