Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
The vessel containing the liquid is known as an _electrolytic cell._ In
fig. 89, A is the cell, which may be of glass or of any other suitable
material, and B is the liquid which is to be electrolyzed. Current enters
by the _positive electrode_ C, also known as the _anode_, traverses the
liquid, and leaves by the _negative electrode_, or _cathode_, D.
[Illustration: FIG. 90.--Modern apparatus for decomposing water by
electrolysis. Platinum electrodes P and P′ are placed at the bottom of two
upright tubes O and H, and are connected to the terminals T and T′ by
platinum wires, which are fused through the glass of the tubes. These
tubes have glass stop cocks S and S′ at their upper ends, and at their
lower ends are connected by a short glass tube, from the center of which
rises the large central tube which expands with a bulb at its upper end,
which is open at the top. The three tubes can be filled with acidulated
water from the central tube, the previously contained air being allowed to
escape through the stop cocks, which are afterwards closed. If it be so
filled, and the terminal T be attached to the positive and T′ to the
negative pole of a suitable battery, bubbles of gas will be observed to
rise from the plates P and P′, and finding their way to the top of the
respective tubes, will displace the liquid, which will be driven into the
open central tube. The gas rising from the anode P is oxygen (O), and that
rising from the cathode P′ is hydrogen (H). If the tubes are graduated,
the latter will be found to occupy about twice the volume of the former.
The proportion is theoretically 2 to 1; however, on account of the
different solubilities of the two gases in water, oxygen being the more
soluble of the two, is deficient in quantity.]
The passage of current through the water splits up its molecules into
their constituent atoms of oxygen and hydrogen, the former being given off
in bubbles at the anode, and the latter at the cathode.
When current is passed through a solution of copper sulphate between
platinum electrodes, the liquid is decomposed, atoms of copper being
deposited at the cathode, bubbles of oxygen being given off at the anode,
and sulphuric acid being formed in the liquid, which latter becomes more
and more acid as the copper is withdrawn.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account