Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
In his later days Berzelius was much engaged in controversy with the
leaders of the new school, the rise and progress of which will be traced in
the next chapter, but throughout this controversy he found time to add many
fresh facts to those already known. He continued his researches until his
death in 1848.
The work of the great Swedish chemist is characterized by thoroughness in
all its parts: to him every fact appeared to be of importance; although now
perhaps only an isolated fact, he saw that some day it would find a place
in a general scheme of classification. He worked in great measure on the
lines laid down by Dalton and Davy; the enormous number and accuracy of his
analyses established the law of multiple proportions on a sure basis, and
his attempts to determine the constitution of compound atoms, while
advancing the atomic theory of Dalton, drew attention to the all-important
distinction between atom and molecule, and so prepared chemists for the
acceptance of the generalization of Avogadro. The electro-chemical
conceptions of Davy were modified by Berzelius; they were shorn of
something of their elasticity, but were rendered more suited to be the
basis of a rigid theory.
* * * * *
At the close of this transition period from the Lavoisierian to the modern
chemistry, we find analytical chemistry established as an art; we find the
atomic theory generally accepted, but we notice the existence of much
confusion which has arisen from the non-acceptance of the distinction made
by Avogadro between atom and molecule; we find the analogies between
chemical affinity and electrical energy made the basis of a system of
classification which regards every compound atom (or molecule) as built up
of two parts, in one of which positive, and in the other negative
electricity predominates; and accompanying this system of classification we
find that an acid is no longer regarded as necessarily an oxygen compound,
but rather as a compound possessed of certain properties which are probably
due to the arrangement of the elementary atoms, among which hydrogen
appears generally to find a place; we find that salts are for the most part
regarded as metallic derivatives of acids; and we find that by the
decomposition of the supposed elementary substances, potash, soda, lime,
etc., the number of the elements has been extended, the application of a
new instrument of research has been brilliantly rewarded, and the
Lavoisierian description of "element" as the "attained, not the attainable,
limit of research" has been emphasized.
FOOTNOTES:
[9] The history and meaning of these terms is considered on p. 171, _et
seq._
[10] For an explanation of this expression, "chemical affinity," see p.
206, _et seq._
[11] These views have been already explained on pp. 182, 183.
CHAPTER V.
THE WORK OF GRAHAM.
_Thomas Graham_, 1805-1869.
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