Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
"Can any facts," asks Graham, "more strikingly illustrate the maxim that in
Nature there are no abrupt transitions, and that distinctions of class are
never absolute?"
In the properties of colloids and crystalloids Graham saw an index of
diversity of molecular structure. The smallest individual particle of a
colloid appeared to him to be a much more complex structure than the
smallest particle of a crystalloid. The colloidal molecule appeared to be
formed by the gathering together of several crystalloidal molecules; such a
complex structure might be expected readily to undergo change, whereas the
simpler molecule of a crystalloid would probably present more definite and
less readily altered properties.
In this research Graham had again, as so often before, arrived at the
conception of various orders of small particles. In the early days of the
Daltonian theory it seemed that the recognition of atoms as ultimate
particles, by the placing together of which masses of this or that kind of
matter are produced, would suffice to explain all the facts of chemical
combinations; but Dalton's application of the term "atom" to elements and
compounds alike implied that an atom might itself have parts, and that one
atom might be more complex than another. The way was thus already prepared
for the recognition of more than one order of atoms, a recognition which
was formulated three years after the appearance of Dalton's "New System" in
the statement of Avogadro, "Equal volumes of gases contain equal numbers of
molecules;" for we have seen that the application of this statement to
actually occurring reactions between gases obliges us to admit that the
molecules of hydrogen, oxygen and many other elementary gases are composed
of two distinct parts or atoms.
Berzelius it is true did not formally accept the generalization of
Avogadro; but we have seen how the conception of atom which runs through
his work is not that of an indivisible particle, but rather that of a
little individual part of matter with definite properties, from which the
mass of matter recognizable by our senses is constructed, just as the wall
is built up of individual bricks. And as the bricks are themselves
constructed of clay, which in turn is composed of silica and alumina, so
may each of these little parts of matter be constructed of smaller parts;
only as clay is not brick, and neither silica nor alumina is clay, so the
properties of the parts of the atom--if it has parts--are not the
properties of the atom, and a mass of matter constructed of these parts
would not have the same properties as a mass of matter constructed of the
atoms themselves.
Public-domain text, read in full here on John Shaqi.
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