Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
A monovalent element is regarded as one the atom of which acts on and is
acted on by only one atom of hydrogen in a molecule; a divalent as one, the
atom of which acts on and is acted on by two atoms of hydrogen--or other
monovalent element--in a molecule; a trivalent element as one, the atom of
which acts on and is acted on by three atoms of hydrogen--or other
monovalent element--in a molecule; and so on.
The fact that there often exist several compounds of carbon, the molecules
of which are composed of the same numbers of the same atoms, finds a
partial explanation by the aid of this conception of the elementary atom as
a little particle of matter capable of binding to itself a certain limited
number of other atoms to form a compound molecule. For if the observed
properties of a compound are associated with a certain definite arrangement
of the elementary atoms within the molecules of that compound, it would
seem that any alteration in this arrangement ought to be accompanied by an
alteration in the properties of the compound; in other words, the existence
of more than one compound of the same elements united in the same
proportions becomes possible and probable.
I have said that such compounds exist: let me give a few examples.
The alchemists poured a stream of mercury on to molten sulphur, and
obtained a black substance, which was changed by heat into a brilliantly
red-coloured body. We now know that the black and the red compounds alike
contain only mercury and sulphur, and contain these elements united in the
same proportions.
Hydrogen, carbon, nitrogen and oxygen unite in certain proportions to
produce a mobile, colourless, strongly acid liquid, which acts violently on
the skin, causing blisters and producing great pain: if this liquid is
allowed to stand for a little time in the air it becomes turbid, begins to
boil, gets thicker, and at last explodes, throwing a white pasty substance
about in all directions. This white solid is inodorous, is scarcely acid to
the taste, and does not affect the skin; yet it contains the same elements,
united in the same proportions, as were present in the strongly acid,
limpid liquid from which it was produced.
Two substances are known each containing carbon and hydrogen united in the
same proportions: one is a gas with strong and irritating odour, and
exerting a most disagreeable action on the eyes; the other is a clear,
limpid, pleasant-smelling liquid.
Phosphorus is a very poisonous substance: it readily takes fire in the air
at ordinary temperatures, so that it must be kept under water; but a
modification of phosphorus is known, containing no form of matter other
than phosphorus, which is non-poisonous, does not take fire easily, and may
be handled with safety.
Public-domain text, read in full here on John Shaqi.
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