Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Let us now turn to another part of this subject. By a special arrangement
of apparatus it is possible to observe the spectrum of the light emitted by
a glowing vapour, parts of which are hotter than other parts, and to
compare the lines in the spectrum of the light coming from the hottest
parts with the lines in the spectrum of the light coming from the cooler
parts of the vapour. If this is done for sodium vapour, certain lines are
apparent in all the spectra, others only in the spectrum of the light
coming from the hottest parts of the sodium vapour: the former lines are
called "long lines," the latter "short lines." A rough representation of
the long and short lines of sodium is given in Fig. 7.
[Illustration: Fig. 7.--Long and short lines of sodium.]
Now, suppose that the lines in the spectrum of the light emitted by glowing
manganese vapour have been carefully mapped, and classed as long and short
lines: suppose that the same thing has been done for the iron lines: now
let a little manganese be mixed with much iron, let the mixture be
vaporized, and let the light which is emitted be decomposed by the prism of
a spectroscope, it will be found that the long lines of manganese alone
make their appearance; let a little more manganese be added to the mixture,
and now some of the shorter lines due to manganese begin to appear in the
spectrum. Hence it has been concluded by Lockyer that if the spectrum of
the light emitted by the glowing vapour of any element--call it A--is free
from the long lines of any other element--say element B--this second
element is not present as an impurity in the specimen of element A which is
being examined. Lockyer has applied this conclusion to "purify" various
elementary spectra.
The spectrum of element A is carefully mapped, and the lines are divided
into long and short lines, according as they are noticed in the spectrum of
the light coming from all parts of the glowing vapour of A, or only in the
spectrum of the light which comes from the hotter parts of that vapour. The
spectra of elements B and C are similarly mapped and classified: then the
three spectra are compared; the longest line in the spectrum of B is noted,
if this line is found in the spectrum of A, it is marked with a negative
sign--this means that so far as the evidence of this line goes B is present
as an impurity in A; the next longest B line is searched for in the
spectrum of A--if present it also is marked with a negative sign; a similar
process of comparison and elimination is conducted with the spectra of A
and C. In this way a "purified" spectrum of the light from A is
obtained--a spectrum, that is, from which, according to Lockyer, all lines
due to the presence of small quantities of B and C as impurities in A have
been eliminated.
[Illustration: Fig. 8.]
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