Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But when the heat of the battle was over and the bitterness of the strife
forgotten, it was found that, although many pinnacles of the dualistic
castle had been shattered, the foundation and great part of the walls
remained; and, strange to say, the men who led the attack were content that
these should remain.
The atom could no longer be regarded as always composed of two parts, but
must be looked on rather as one whole, the properties of which are defined
by the properties and arrangements of all its parts; but the conception of
the atom as a structure, and the assurance that something could be inferred
regarding that structure from a knowledge of the reactions and general
properties of the whole, remained when Dumas and Liebig had replaced the
dualism of Berzelius by the unitary theory of modern chemistry; and these
conceptions have remained to the present day, and are now ranked among the
leading principles of chemical science; only we now speak of the "molecule"
where Berzelius spoke of the "atom."
Along with these advances made by Dumas, Liebig and others in rendering
more accurate the general conception of atomic structure, we found that
the recognition of the existence of more than one order of small particles
was daily gaining ground in the minds of chemists.
The distinction between what we now call atoms and molecules had been
clearly stated by Avogadro in 1811; but the times were not ripe. The mental
surroundings of the chemists of that age did not allow them fully to
appreciate the work of Avogadro. The seed however was sown, and the
harvest, although late, was plentiful.
We saw that Dumas accepted, with some hesitation, the distinction drawn by
Avogadro, but that failing to carry it to its legitimate conclusion, he did
not reap the full benefit of his acceptance of the principle that the
smallest particle of a substance which takes part in a physical change
divides into smaller particles in those changes which we call chemical.
To Gerhardt and Laurent we owe the full recognition, and acceptance as the
foundation of chemical classification, of the atom as a particle of matter
distinct from the molecule; they first distinctly placed the law of
Avogadro--"Equal volumes of gases contain equal numbers of molecules"--in
its true position as a law, which, resting on physical evidence and
dynamical reasoning, is to be accepted by the chemist as the basis of his
atomic theory. To the same chemists we are indebted for the formal
introduction into chemical science of the conception of types, which, as we
found, was developed by Frankland, Kekule, and others, into the modern
doctrine of equivalency of groups of elementary atoms.
Public-domain text, read in full here on John Shaqi.
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