Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
A very important paper was published in 1801, on the "Constitution of Mixed
Gases, etc.," wherein Dalton asserted that the total pressure of a mixture
of two gases on the walls of the containing vessel is equal to the sum of
the pressures of each gas; in other words, that if one gas is removed the
pressure now exerted by the remaining gas is exactly the same as was
exerted by that gas in the original mixture. In a paper published much
later (1826), when his views and experiments on this subject were matured,
he writes: "It appears to me as completely demonstrated as any physical
principle, that whenever two or more ... gases or vapours ... are put
together, either into a limited or unlimited space, they will finally be
arranged each as if it occupied the whole space, and the others were not
present; the nature of the fluids and gravitation being the only
efficacious agents."
This conclusion was followed out and extended in a paper published in 1803,
on the absorption of gases by water and other liquids, wherein he states
that the amount of each gas _mechanically dissolved_ by a liquid from a
mixture of gases depends only on the quantity of _that_ gas in the mixture,
the other gases exerting no influence in this respect.
Dalton now considered the variation in the pressures of various gases
caused by increasing or decreasing temperature, and then proceeded to
discuss the relations which exist between the volumes of gases and the
temperature at which these volumes are measured. He concluded that "all
elastic fluids" under the same pressure expand equally by heat: and he adds
the very important remark, "It seems, therefore, that general laws
respecting the absolute quantity and the nature of heat are more likely to
be derived from the study of elastic fluids than of other substances"--a
remark the profound truth of which has been emphasized by each step in the
advances made in our conception of the nature of heat since the time of
Dalton.
In these papers on the "Constitution of Mixed Gases" Dalton also describes
and illustrates a method whereby the actual amount of water vapour in a
given bulk of atmospheric air may be found from a knowledge of the
dew-point of that air, that is, the temperature at which the deposition of
water in the liquid form begins. The introduction of this method for
finding the humidity of air marks an important advance in the history of
meteorology.
In this series of papers published within the first three years of the
present century Dalton evidently had before his mind's eye a picture of a
gas as a quantity of matter built up of small but independent particles; he
constantly speaks of pressures between the small particles of elastic
fluids, of these particles as repelling each other, etc. In his "New
System" he says, "A vessel full of any pure elastic fluid presents to the
imagination a picture like one full of small shot."
Public-domain text, read in full here on John Shaqi.
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