Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
It is very important to notice that Dalton makes use of this conception of
small particles to explain purely physical experiments and operations.
Although we know that during these years he was thinking much of "chemical
combinations," yet we find that it was his observations on the weather
which led him to the conception--a purely physical conception--of each
chemically distinct gas as being built up of a vast number of small,
equally heavy particles. A consideration of these papers by Dalton on the
constitution of mixed gases shows us the method which he pursued in his
investigations. "The progress of philosophical knowledge," he says, "is
advanced by the discovery of new and important facts; but much more when
these facts lead to the establishment of general laws." Dalton always
strove to attain to general laws. The facts which he describes are
frequently inaccurate; he was singularly deficient in manipulation, and he
cannot claim a high place as a careful experimenter. He was however able to
draw general conclusions of wide applicability. He seems sometimes to have
stated a generalization in definite form before he had obtained any
experimental verification of it.
In the year 1802 Dalton conducted an examination of air from various
localities, and concluded that one hundred volumes of air are composed of
twenty-one volumes of oxygen and seventy-nine volumes of nitrogen. This
appears to have been his first piece of purely chemical work. But in the
next year he again returns to physical phenomena. In the paper already
referred to, on the absorption of gases by water and other liquids,
published in this year, he had stated that "All gases that enter into water
and other liquids by means of pressure, and are wholly disengaged again by
the removal of that pressure, are _mechanically_ mixed with the liquid, and
not _chemically_ combined with it." But if this be so, why, he asked, does
not water mechanically dissolve the same bulk of every kind of gas? The
answer which he gives to this question is found at the close of the paper;
to the student of chemistry it is very important:--
"This question I have duly considered, and though I am not yet able to
satisfy myself completely, I am nearly persuaded that the circumstance
depends upon the weight and number of the ultimate particles of the several
gases, those whose particles are lightest and single being least
absorbable, and the others more, accordingly as they increase in weight and
complexity. An inquiry into the relative weights of the ultimate particles
of bodies is a subject, as far as I know, entirely new. I have lately been
prosecuting this inquiry with remarkable success. The principle cannot be
entered upon in this paper; but I shall just subjoin the results, as far as
they appear to be ascertained by my experiments." Then follows a "_Table
of the relative weights of the ultimate particles of gaseous and other
bodies._" The following numbers, among others, are given:--
Public-domain text, read in full here on John Shaqi.
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