Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But consider the combination of a gaseous element with hydrogen; let us
take the case of hydrogen and chlorine, which unite to form gaseous
hydrochloric acid, and let us determine the volumes of the uniting elements
and the volume of the product. Here is a statement of the results: one
volume of hydrogen combines with one volume of chlorine to form two volumes
of hydrochloric acid. Assume any number of molecules we please in the one
volume of hydrogen--say ten--there must be, by Avogadro's law, also ten
molecules in the one volume of chlorine; but inasmuch as the volume of
hydrochloric acid produced is double that of either the hydrogen or the
chlorine which combined to form it, it follows, by the same law, that
twenty molecules of hydrochloric acid have been formed by the union of ten
molecules of hydrogen with ten molecules of chlorine. The necessary
conclusion is that each hydrogen molecule and each chlorine molecule has
split into two parts, and that each half-molecule (or atom) of hydrogen has
combined with one half-molecule (or atom) of chlorine, to produce one
compound molecule of hydrochloric acid.
Therefore we conclude that the hydrogen molecule is composed of two atoms,
and that the chlorine molecule is also composed of two atoms; and as
hydrogen is to be our standard element, we say that if the atom of hydrogen
weighs one, the molecule of the same element weighs two.
It is now easy to find the _molecular weight_ of any gas; it is only
necessary to find how many times heavier the given gas is than hydrogen,
the weight of the latter being taken as 2. Thus, oxygen is sixteen times
heavier than hydrogen, but 1: 16 = 2: 32, therefore the molecule of oxygen
is thirty-two times heavier than the molecule of hydrogen. Ammonia is eight
and a half times heavier than hydrogen, but 1: 8-1/2 = 2: 17, therefore the
molecule of ammonia is seventeen times heavier than the molecule of
hydrogen. This is what we more concisely express by saying "the molecular
weight of oxygen is 32," or "the molecular weight of ammonia is 17," etc.,
etc.
Now, we wish to determine the _atomic weight_ of oxygen; that is, we wish
to find how many times the oxygen atom is heavier than the atom of
hydrogen. We make use of Avogadro's law and of the definition of "atom"
which has been deduced from it (see p. 142).
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