Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Up to this time the term "alkali" had been applied to almost any substance
having the properties which I have just enumerated; but this group of
substances was divided by Van Helmont and his successors into _fixed
alkali_ and _volatile alkali_, and fixed alkali was further subdivided into
_mineral alkali_ (what we now call soda) and _vegetable alkali_ (potash).
About the same time acids were likewise divided into three groups;
_vegetable_, _animal_, and _mineral acids_. To the properties by which
alkali was distinguished, viz. cleansing power and action on vegetable
colouring matters, Stahl (the founder of the phlogistic theory) added that
of combining with acids. When an acid (that is, a sour-tasting substance
which dissolves most earthy matters and turns vegetable blues to red) is
added to an alkali (that is, a substance which feels soap-like to the
touch, which does not dissolve many earthy matters, and which turns many
vegetable reds to blue) the properties of both acid and alkali disappear,
and a new substance is produced which is not characterized by the
properties of either constituent. The new substance, as a rule, is without
action on earthy matters or on vegetable colours; it is not sour, nor is it
soapy to the touch like alkali; it is _neutral_. It is _a salt_. But,
although Stahl stated that an alkali is a substance which combines with an
acid, it was not until a century later that these three--alkali, acid,
salt--were clearly distinguished.
But the knowledge that a certain group of bodies are sour and dissolve
minerals, etc., and that a certain other group of bodies are nearly
tasteless and do not dissolve minerals, etc., was evidently a knowledge of
only the outlying properties of the bodies; it simply enabled a term to be
applied to a group of bodies, which term had a definite connotation.
_Why_ are acids acid, and _why_ are alkalis alkaline?
Acids are acid, said Becher (latter part of seventeenth century), because
they all contain the same principle, viz. the primordial acid. This
primordial acid is more or less mixed with earthy matter in all actual
acids; it is very pure in spirits of salt.
Alkalis are alkaline, said Basil Valentine (beginning of the sixteenth
century), because they contain a special kind of matter, "the matter of
fire."
According to other chemists (_e.g._ J. F. Meyer, 1764), acids owe their
acidity to the presence of a sharp or biting principle got from fire.
Acids, alkalis and salts _all_ contain, according to Stahl (beginning of
the eighteenth century), more or less _primordial acid_. The more of this a
substance contains, the more acid it is; the less of this it contains, the
more alkaline it is.
Public-domain text, read in full here on John Shaqi.
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