Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Strange we may say that this discovery did not induce Black to prosecute
the study of caustic alkalis: surely he would have anticipated Davy, and
have been known as the discoverer of potassium and sodium.
In the time of Stahl the name "salt" was applied, as we have learned, to
the substance produced by the union of an acid with an alkali; but the same
word was used by the alchemists with an altogether different signification.
Originally applied to the solid matter obtained by boiling down sea-water,
and then extended to include all substances which, like this solid matter,
are very easily dissolved by water and can be recovered by boiling down
this solution, "salt" was, in the sixteenth and seventeenth centuries, the
name given to one of the hypothetical principles or elements. Many kinds of
matter were known to be easily dissolved by water; the common possession of
these properties was sought to be accounted for by saying that all these
substances contained the same principle, namely, _the principle of salt_. I
have already tried to indicate the reasoning whereby Boyle did so much to
overthrow this conception of salt. He also extended our knowledge of
special substances which are now classed as salts. The chemists who came
after Boyle gradually reverted to the older meaning of the term "salt,"
adopting as the characteristics of all substances placed in this class,
ready solubility in water, fusibility, or sometimes volatility, and the
possession of a taste more or less like that of sea-salt.
Substances which resembled salts in general appearance, but were insoluble
in water, and very fixed in the fire, were called "earths"; and, as was
generally done in those days, the existence of a primordial earth was
assumed, more or less of which was supposed to be present in actual earths.
This recognition of the possibility of more or less of the primordial earth
being present in actually occurring earths, of course necessitated the
existence of various kinds of earth. The earths were gradually
distinguished from each other; lime was recognized as a substance distinct
from baryta, baryta as distinct from alumina, etc.
Stahl taught that one essential property of an earth was fusibility by
fire, with production of a substance more or less like glass. This property
was possessed in a remarkable degree by quartz or silica. Hence silica was
regarded as the typical earth, until Berzelius, in 1815, proved it to be an
acid. But the earths resembled alkalis, inasmuch as they too combined with,
and so neutralized, acids.
There is an alkali hidden in every earth, said some chemists.
An alkali is an earth refined by the presence of acid and combustible
matter, said others.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account