Another principle, almost equally general in its applicability, is
that of the dissipation of energy, for which we are indebted in the
first instance to Sir William Thomson. All forms of energy may be
converted into heat, and heat tends so to diffuse itself throughout
all bodies as to bring them to one uniform temperature. This is its
ultimate state of degradation, and from that state no methods with
which we are acquainted can transform any portion of it. When energy
is possessed by a system in consequence of the relative positions or
motions of bodies which we can handle, and whose movements we may
control, the whole of the energy may be employed in doing any work we
please; in fact, it is all _available_ for our purpose, or its
_availability_ may be said to be perfect. Energy in any other form is
limited in its availability by the conditions under which we can place
it. For example, the energy of chemical action in a battery may be
used to produce a current, and this to drive a motor by which
mechanical work is effected, but some of the energy must inevitably be
degraded into the form of heat by the resistance of the battery and of
the conductor, and this portion will be greater as the rate of doing
work is increased. The ratio of the quantity of energy which can be
employed for mechanical purposes with the means at our disposal, to
the whole amount present, is called the _availability_ of the energy.
All forms of energy may be wholly converted into heat, but only a
fraction of any quantity of heat can be transformed into higher forms
of energy, and this depends on the temperature of the source of heat
and of the coldest body which can be employed as a condenser, being
greater the greater the difference between the temperatures of the
source and condenser, and the lower the temperature of the latter. In
every operation which takes place in nature there is a degradation of
energy, and though some portion of the energy may be raised in
availability, another portion is lowered, so that on the whole the
availability is diminished. Thus, in the case of the heat-engine, work
can be obtained from heat only by allowing another portion of the heat
to fall in temperature; and, as originally stated by Sir William
Thomson, "it is impossible, by means of inanimate material agency, to
obtain mechanical effect from any portion of matter by cooling it
below the temperature of the coldest of the surrounding objects," and
to leave the working substance in the same condition in which it was
at the commencement of the operations. Accepting this principle,
Professor James Thomson showed that increase of pressure must lower
the freezing point of water, for otherwise it would be possible to
construct an engine which, working by the expansion of water in
freezing, would continue to do work by cooling a body below the
temperature of any other body available, and he calculated the amount
of pressure necessary to lower the freezing point through one degree.
Public-domain text, read in full here on John Shaqi.
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