Any theory which is brought forward to explain a phenomenon, or any
process which is proposed to effect any operation, must in the first
instance submit to the test of the application of these two principles
of conservation and dissipation of energy; and any proposal which
fails to bear these tests may be at once rejected. The essential
feature of the science of to-day is its quantitative character. We
must, for instance, not only know that radiant energy comes to us from
the sun, but we must learn how much energy is annually received by the
earth in this way; and, in the next place, how much energy is radiated
by the sun in all directions in the same time. When we have learned
this, we want to know what is the source of this energy; and no theory
of the sun which does not enable us to explain how this constant
expenditure of energy is maintained can be accepted. Last century it
was possible to believe, with Sir William Herschel, that the greater
part of the sun's mass is comparatively cool, and that it is
surrounded by only a thin sheet of flame. To-day such a theory would
be rejected at once, simply because the thin shell of flame could not
provide energy for the solar radiation for any considerable time. The
contact theory of the galvanic cell, as originally enunciated, fell to
the ground for a similar reason. The simple contact of dissimilar
metals could afford no continuous supply of energy to sustain the
current. Applied to the steam-engine, the doctrine of energy teaches
us, not only that, corresponding to the combustion of a pound of coal,
there is a definite quantity of work which is the mechanical
equivalent of the heat generated, and is such that no engine of which
we can conceive is capable of deriving from the combustion of the
pound of coal a greater amount of work, but it teaches us that there
is a further limitation fixed to the amount of work obtainable. This
limitation depends upon the range of temperature at our command; and,
when the range is known, we can express the amount of energy
realizable by a perfect engine working through that range as a
definite fraction of the whole energy corresponding to the heat of
combustion of the fuel. Thus, if we find that a particular engine
realizes only 15 per cent. of the energy of its fuel in work done, we
must not suppose that mechanical improvements in the engine would
enable us to realize any considerable portion of the other 85 per
cent.; for it may be that a theoretically perfect engine, working with
its boiler and condenser at the same temperatures as those of the
engine considered, could only realize 25 per cent. of the energy of
the fuel, reducing the margin for improvement from 85 to 10 per cent.,
as long as the range of temperature is unaltered. To improve the
efficiency beyond this limit, the range of temperature must be
increased, that is, generally, hotter steam must be used.
Public-domain text, read in full here on John Shaqi.
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