History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
On the practical side chemistry made considerable progress. Analysis—a
term originally applied by Boyle—greatly advanced. It was, of course,
mainly qualitative; but, thanks to the labours of Boyle, Hoffmann,
Marggraf, Scheele, Bergman, Gahn, and Cronstedt, certain reactions
and reagents came to be systematically applied to the recognition of
chemical substances, and the precision with which these reagents were
used led to the detection of hitherto unknown elements. The beginnings
of a quantitative analysis were made even before the time of Boyle,
but its principles were greatly developed by him, and were further
extended by Homberg, Marggraf, and Bergman. Marggraf accurately
determined the amount of silver chloride formed by adding common salt
to a solution of a known weight of silver, and Bergman first pointed
out that estimations of substances might be conveniently made by
weighing them in the form of suitably prepared compounds, which, it
was implicitly assumed, were of uniform and constant composition. The
foundations of an accurate system of gaseous analysis were made by
Cavendish; and various forms of physical apparatus were applied to the
service of chemistry.
To the elements which were known prior to Boyle’s time, although not
recognised as such, there were added phosphorus (Brand, 1669), nitrogen
(Rutherford), chlorine (Scheele, 1774), manganese (Gahn, 1774), cobalt
(Brandt, 1742), nickel (Cronstedt, 1750), and platinum (Watson, 1750).
Baryta was discovered by Scheele, and strontia by Crawford. Phosphoric
acid was discovered by Boyle, and its true nature determined by
Marggraf; Cavendish first made known the composition of nitric acid.
As already stated, Scheele first isolated molybdic and tungstic acids
and determined the existence of a number of the organic acids (p. 75).
Other discoveries—such as the true nature of limestone and _magnesia
alba_ and their relations respectively to lime and magnesia by Black,
the many gaseous substances by Priestley, and the compound nature of
water by Cavendish—have already been referred to.
Technical chemistry also greatly developed during the eighteenth
century, thanks to the efforts of Gahn, Marggraf, Duhamel, Reaumur,
Macquer, Kunkel, and Hellot; and many important industrial
processes—such as the manufacture of sulphuric acid by Ward of
Richmond, and subsequently by Roebuck at Birmingham, and the Leblanc
process of conversion of common salt into alkali—had their origin
during this period.
CHAPTER VIII
LAVOISIER AND LA RÉVOLUTION CHIMIQUE
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