History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Towards the latter half of the eighteenth century clearer views
began to be held concerning the relations of atmospheric air to the
phenomena of combustion and of calcination; many half-forgotten facts
relating to these phenomena were recalled, and the inconsistencies
and insufficiency of phlogiston as a dogma became gradually manifest.
Three cardinal facts conspired to bring about its overthrow—the
isolation of oxygen by Priestley; the recognition by him of the nature
of atmospheric air, and of the fact that one of its constituents
is oxygen; and, lastly, the discovery by Cavendish that water is a
compound, and that its constituents are oxygen and hydrogen. The
significance of these facts was first clearly grasped by Lavoisier, and
to him is due the credit of their true interpretation. By reasoning
and experiment he proved conclusively that all ordinary phenomena of
burning are so many instances of the combination of the oxygen of the
air with the combustible substance; that calcination is a process of
combination of the oxygen in the air with the metal, which thereby
increases in weight by the amount of oxygen combined. Water—no longer a
simple substance—is formed by the union, weight for weight, of oxygen
and hydrogen. Lavoisier’s reasoning was so sound and his experimental
evidence so complete that his views gradually gained acceptance in
France. The phlogiston myth was thus exploded. Inspired by Lavoisier,
a small band of French chemists—Berthollet, Fourcroy, Guyton de
Morveau—thereupon set to work to remodel the system of chemistry
and to recast its nomenclature so as to eliminate all reference
to phlogiston. The very names “oxygen,” “hydrogen,” “nitrogen,”
corresponding respectively to the “dephlogisticated air,” “phlogiston,”
and “phlogisticated air” of Priestley, were coined by the new French
school. For a time _le principe oxygine_ was regarded by this school
in much the same relation as phlogiston was regarded by Stahl and his
followers. The one fetich was exchanged for the other. The combustible
principle—phlogiston—was renounced for the acidifying principle—oxygen.
The new chemistry for a time centred itself round oxygen, just as
the old chemistry had centred itself round phlogiston. The views of
the French school met with no immediate acceptance in Germany, the
home of phlogistonism, or in Sweden or England, possibly owing, to
some extent, to national prejudices. The spirit of revolution, even
although it might be an intellectual revolution, had not extended to
these countries. Priestley, Cavendish, and Scheele could not be induced
to accept the new doctrine. It was, however, accepted by Black, and
its principles taught by him in Edinburgh; and before the end of the
century it had practically supplanted phlogistonism in this country.
Some of those who, like Kirwan, had energetically opposed the new
theory ended by enthusiastically embracing it. Its introduction into
Germany was mainly due to the influence of Klaproth.
Public-domain text, read in full here on John Shaqi.
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