History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Other workers took up the subject, notably
Wroblewski and Olszewki in Poland, Dewar in England, and Kammerlingh
Onnes in Holland; and the liquefaction of all the gases has now been
accomplished.
The following table shows the _absolute_ boiling-(B.P.) and
melting-points (M.P.), critical points (C.P.), and pressures
(C.Press.), together with the density (D) at their boiling-points of a
number of liquefied gases:
C.
B. P. M. P. C. P. Press. D.
_degrees_ _degrees_ _degrees_ _m._
Helium 4.5 —— —— —— 0.15
Hydrogen 20 15 35 11.6 0.06
Oxygen 90.5 below 50 154 44 1.131
Nitrogen 77.5 60 124 20.9 0.791
Methane 108.3 —— 191 42.4 0.416
Ethylene 169.5 104 282 44 0.571
Fluorine 186 40 —— —— 1.11
Chlorine 239.6 —— —— —— 1.507
Ammonia 234.5 197.5 404 85.9 ——
Neon 30.40 —— below 65 —— ——
Argon 86.90 —— 155.6 40.2 1.212
Krypton 121.33 —— 210.5 41.2 2.155
Xenon 163.9 —— 287.8 43.5 3.52
The principle of the Cailletet method of effecting the liquefaction of
oxygen had been theoretically and experimentally studied by Joule and
Lord Kelvin many years previously. It was extended by Siemens and has
been applied by Linde and Hampson to the construction of machinery for
the production of liquid air on a large scale, without the use of any
intermediate refrigerant.
It is now readily possible to procure considerable quantities of liquid
air, and even of liquid hydrogen. By the evaporation of liquid hydrogen
temperatures approaching the _absolute zero_—that is, 273° C. below
the melting-point of ice—can now be reached. Incidentally there has
been developed a special field of inquiry relating to the behaviour of
substances at low temperatures.
[Illustration: SIR JAMES DEWAR.]
The pioneers in this field have been Dewar in England and Kammerlingh
Onnes in Holland. Research at low temperatures, indeed, has been
the main feature of the work of the Royal Institution of Great
Britain during the last twenty years. It has included observations
at temperatures approaching the absolute zero, on the electrical
resistivity of metals and alloys, on the behaviour of so-called
insulators, on changes in the cohesive force of metals, on the
dielectric constants of frozen electrolytes, on the influence of cold
on magnetisation and on magnetic permeability, and on the optical
behaviour of bodies, on vital phenomena at low temperatures, and on the
influence of cold on chemical change.
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