History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Dewar has succeeded in liquefying and solidifying large quantities
of hydrogen, and has studied its properties at low temperatures.
Liquid hydrogen is transparent and colourless. It is a non-conductor
of electricity, and gives no absorption spectrum. It freezes into an
ice-like solid, devoid of metallic properties. Dewar has made use of
the property possessed by charcoal of occluding gases, especially
at low temperatures, in the production of high vacua, and in the
separation of gases; and he has also determined the molecular heat
of absorption by charcoal of various gases. He has employed liquid
air, liquid nitrogen, and liquid hydrogen as calorimetric agents, and
has determined by means of them the heat capacities of a number of
substances at very low temperatures. Lastly, his ingenious contrivance
of silvered vacuum protected vessels, now introduced into commerce
under the name of “Thermos flasks,” has greatly facilitated the
manipulation of liquefied gases for experimental purposes.
CHAPTER VI
THE PERIODIC LAW
In an anonymous essay “On the Relation between the Specific Gravities
of Bodies in their Gaseous State and the Weights of their Atoms,”
published in Thomson’s _Annals of Philosophy_ in 1815, the attempt
was made to indicate certain consequences which seem to follow from
Dalton’s law of gaseous volumes, as generalised by Gay Lussac. The
author of this essay was subsequently discovered to be a medical
student named William Prout, noteworthy as having been one of the
first to point out the suggestiveness of the numerical relationships
which occur among the atomic weights of the elements. This paper is
usually assumed to contain the statement that the atomic weights of the
elements are multiples of that of hydrogen. As a fact, however, this
hypothesis is nowhere explicitly stated in the paper. The inference was
practically due to Thomson, who strove to support it by experimental
proof of so weak a character as to draw forth the remark of Berzelius
that much of it appeared to have been made at the writing-desk.
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