History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
The reader who desires a fuller exposition of the principles of the
periodic law must be referred to special treatises on the subject, or
to the larger manuals on general chemistry. It must, however, be stated
that, while many facts discovered since the original promulgation of
the principle and since its development by Lothar Meyer, Carnelley,
Thomsen, and others, are consistent with the law, other facts, some
of which were known before 1870, are apparently out of harmony with
it, or at all events await a fuller interpretation. For example,
tellurium is not in its proper place in the scheme if its atomic
weight, 127.5, has been correctly ascertained. Cobalt (58.97) and
nickel (58.68) have atomic weights so closely accordant that their
properties and those of their corresponding compounds should be very
similar, and, in fact, almost identical; but such is not the case.
Indeed, it has been said, no prevision of the periodic law would
have led to the discovery of nickel. Similar considerations apply to
manganese, chromium, and iron; the atomic weights of these elements
are less widely different than the differences in their properties and
the divergence in their chemical relationships would seem to require.
The relative positions of argon and potassium are also not consistent
with the law. There are difficulties, too, connected with what we
know at present concerning the atomic weights of the so-called rare
earth metals. In spite, however, of these seeming anomalies, it can
hardly be doubted that the periodic law is as much the expression of
a natural law as is the law of gravitation; although it is possible,
and indeed probable, that, as we now define it, it is only the first
approximation to the truth, and that, as our knowledge becomes more
precise, Mendeléeff’s classification, in its present form, will require
modification and extension, just as Mendeléeff’s own scheme may be said
to be a modification and extension of the attempts at the rational
classification of the chemical elements made by his predecessors.
[Illustration: DMITRI IVANOWITSCH MENDELÉEFF.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account