History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Of course no statical formula can be the ultimate representation of
the constitution of benzene. However convenient and suggestive such a
formula may be, it can be only a transitional phase in its complete
chemical and physical history. Kekulé was early conscious of this
fact, and suggested a dynamical hypothesis based upon a mechanical
conception of valency. This he imagined might represent the number
of contacts with other atoms which a vibrating atom experienced in
the unit of time. Two atoms of tetravalent carbon, each linked by
one combining unit, will experience four oscillations, striking each
other and three other atoms in the unit of time, while the monovalent
hydrogen atom makes only one oscillation. The doubly linked carbon will
collide with its neighbouring atom twice, and also with two other atoms
within the same period. The assumption that the carbon atom has a more
rapid motion than the hydrogen atom is, however, not warranted by the
kinetic theory. Other dynamic formulæ have been proposed by Knorr and
by Collie. Collie and Baly have further suggested that the absorption
bands of benzene observed in the ultra violet of its spectrum point to
synchronous oscillations of its molecule, due to dynamic changes in
the making and breaking of the links between the several pairs of the
carbon atoms, setting up vibrations in the benzene ring comparable with
those of an elastic ring in the act of expanding and contracting.
* * * * *
The large group of the _essential oils_, containing hydrocarbons
similar to oil of turpentine, and classed under the generic term
of _terpenes_, might, from their origin and mode of occurrence, be
expected to be allied in constitution to the aromatic compounds; and
such is found to be the case. The terpenes are isomeric hydrocarbons
of the formula C10H16. They are found sometimes singly, at other times
mixed, in a great variety of plants, associated with _sesquiterpenes_
C15H24, and oxygenated substances, such as camphor, borneol, menthol,
etc., some of which have long been known and valued for their medicinal
properties and technical applications. The elucidation of their
constitution has taxed the skill of many workers during the past
thirty years; but, thanks to the labours of Wallach, Baeyer, Perkin,
Tiemann, Bredt, Komppa, and others, an insight has been gained into
their nature and analogies. They are apparently all cyclic compounds
with certain attributes which connect them with hydrocarbons of the
aliphatic series. _Pinene_, the characteristic constituent of oil
of turpentine, obtained by distilling the resinous exudations of
many species of pines, exists in two modifications, distinguished by
differences in optical activity, known respectively as _australene_,
found in American, Russian, and Swedish turpentine, and _terebenthene_,
found mainly in French turpentine. It would seem from their empirical
formulæ, as well as from their association in nature, that the terpenes
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