7. _Chemical Affinity._--We shall have, in the next Book, to
speak of Chemical Affinity at some length; but since the
ultimate views to which philosophers have been led, induce
them to consider the forces of Affinity as Polar Forces, we
must enumerate these among the examples of Polarity. In
chemical processes, opposites tend to unite, and to
neutralize each other by their union. Thus an _acid_ or an
_alkali_ combine with vehemence, and form a compound, a
neutral salt, which is neither acid nor alkaline.
This conception of contrariety and mutual neutralization,
involves the Idea of Polarity. In the conception as
entertained by the earlier chemists, the Idea enters very
obscurely: but in the attempts which have more recently been
made to connect this relation (of acid and base), with other
relations, the chemical elements have been conceived as
composed of particles which possess poles; _like_ poles
repelling, and _unlike_ attracting each other, as they do in
magnetic and electric phenomena. This is, however, a rude
and arbitrary way of expressing Polarity, and, as may be
easily shown, involves many difficulties which do not belong
to the Idea itself. Mr. Faraday, who has been led by his
researches to a conviction of the polar nature of the forces
of chemical affinity, has expressed their character in a
more general manner, and without any of the machinery of
particles indued with poles. According to his view, chemical
synthesis and analysis must always be conceived as taking
place in virtue of equal and opposite forces, by which the
particles are united or separated. These forces, by the very
circumstance of their being polar, may be transferred from
point to point. For if we conceive a string of particles,
and if the positive force of the first particle {368} be
liberated and brought into action, its negative force also
must be set free: this negative force neutralizes the
positive force of the next particle, and therefore the
negative force of this particle (before employed in
neutralizing its positive force) is set free: this is in the
same way transferred to the next particle, and so on. And
thus we have a positive force active at one extremity of a
line of particles, corresponding to a negative force at the
other extremity, all the intermediate particles reciprocally
neutralizing each other's action. This conception of the
transfer of chemical action was indeed at an earlier period
introduced by Grotthus[4\5], and confirmed by Davy. But in
Mr. Faraday's hands we see it divested of all that is
superfluous, and spoken of, not as a line of particles, but
as 'an axis of power, having [at every point] contrary
forces, exactly equal, in opposite directions.'
[Note 4\5: DUMAS, _Leçons sur la Philosophie Chimique_, p. 401.]
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