only a separation, but a new combination. There is a force
by which the particles of the solvent associate to
themselves the parts dissolved, not a force by which they
repel and dissever them. We are here to imagine not
mechanical action, not violent impulse, not antipathy, but
love, at least if love be the desire of uniting. (Non igitur
hic etiam actiones mechanicæ, non propulsiones violentæ, non
inimicitiæ cogitandæ, sed amicitiæ, si amor dicendus copulæ
cupido.) The novelty of this view is evidenced by the mode
in which he apologizes for introducing it. 'Fateor, paradoxa
hæc assertio.' To Boerhaave, therefore, (especially
considering his great influence as a teacher of chemistry,)
we may {17} assign the merit of first diffusing a proper
view of Chemical Affinity as a peculiar force, the origin of
almost all chemical changes and operations.
[Note 13\6: _Elementa Chemiæ_, Lugd. Bat. 1732, p. 677.]
3. To Boerhaave is usually assigned also the credit of
introducing the _word_ 'Affinity' among chemists; but I do
not find that the word is often used by him in this sense;
perhaps not at all[14\6]. But however this may be, the term
is, on many accounts, well worthy to be preserved, as I
shall endeavour to show. Other terms were used in the same
sense during the early part of the eighteenth century. Thus
when Geoffroy, in 1718, laid before the Academy of Paris his
Tables of Affinities, which perhaps did more than any other
event to fix the Idea of Affinity, he termed them 'Tables of
the Relations of Bodies;' '_Tables des Rapports_:' speaking
however, also, of their 'disposition to unite,' and using
other phrases of the same import.
[Note 14\6: See Dumas, _Leçons de Phil. Chim._ p. 364. Rees'
_Cyclopædia_, Art. Chemistry. In the passage of Boerhaave to
which I refer above, _affinitas_ is rather opposed to, than
identified with, chemical combination. When, he says, the
parts of the body to be dissolved are dissevered by the
solvent, why do they remain united to the particles of the
solvent, and why do not rather both the particles of the
solvent and of the dissolved body collect into homogeneous
bodies by their _affinity_? 'denuo se affinitate suæ naturæ
colligant in corpora homogenea?' And the answer is, because
they possess another force which counteracts this affinity
of homogeneous particles, and makes compounds of different
elements. Affinity, in chemistry, now means the tendency of
_different_ kinds of matter to unite: but it appears, as I
have said, to have acquired this sense since Boerhaave's time.]
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