of Affinity, as far as any person acquainted with chemical
operations could contend for it. For it must be allowed by
all, that solubility, and other collateral circumstances,
influence the course of chemical combinations, since they
determine whether or not there shall take place that contact
of elements without which affinity cannot possibly operate.
[Note 23\6: _Hist. Ind. Sc._ b. xiv. c. iii.]
[Note 24\6: _Chemistry_, p. 199. 6th edition.]
[Note 25\6: _Leçons de Philosophie Chimique_, p. 386.]
8. _Affinity is Definite as to quantity._--In proportion as
chemists obtained a clearer view of the products of the
laboratory as results of the composition of elements, they
saw more and more clearly that these results were definite;
that one element not only preferred to combine with another
of a certain kind, but also would combine with it to a
certain extent and no further, thus giving to the result not
an accidental and variable, but a fixed and constant
character. Thus salts being considered as the result of the
combination of two opposite principles, acid and alkali, and
being termed _neutral_ when these principles exactly
balanced each other, Rouelle (who was Royal Professor at
Paris in 1742) admits of neutral salts with excess of acid,
neutral salts with excess of base, and perfect neutral
salts. Beaume maintained[26\6] against him that there were
no salts except those perfectly neutral, the other classes
being the results of mixture and imperfect {25} combination.
But this question was not adequately treated till chemists
made every experiment with the balance in their hands. When
this was done, they soon discovered that, in each neutral
salt, the proportional weights of the ingredients which
composed it were always the same. This was ascertained by
Wenzel, whose _Doctrine of the Affinities of Bodies_
appeared in 1777. He not only ascertained that the
proportions of elements in neutral chemical compounds are
definite, but also that they are reciprocal; that is, (to
express his results in a manner now employed by chemists),
that if A, a certain weight of a certain acid, neutralize
_m_, a certain weight of a certain base, and B, a certain
weight of a certain other acid, neutralize _n_, a certain
weight of a certain other base; the compound of A and _n_
will also be neutral; as also that of B and _m_. The same
views were again presented by Richter in 1792, in his
_Principles of the Measure of Chemical Elements_. And along
with these facts, that of the combination of elements in
multiple proportions being also taken into account, the
foundations of the Atomic Theory were laid; and that Theory
was propounded in 1803 by Mr. Dalton. That theory, however,
rests upon the Idea of Substance, as well as upon that Idea
of Chemical Affinity which we are here considering; and the
discussion of its evidence and truth must be for the present
deferred.
[Note 26\6: Dumas, _Phil. Chim._ p. 198.]
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