How to Use the Popular Science Library; History of Science; General IndexServiss, Garrett Putman
History
How to Use the Popular Science Library; History of Science; General Index
Serviss, Garrett Putman
Popular science library; Science -- History
Van't Hoff, Pfeffer, and others noticed that when two solutions are
brought together, if one is more concentrated than the other, diffusion
begins in the concentrated and extends to the weaker solution. This
shows a talent force in concentrated solutions which is now known as
osmotic pressure. Van't Hoff and Arrhenius showed that for comparable
concentrations the osmotic pressure of a solution is exactly equal to
the pressure of a gas. These discoveries led to a brilliant series of
investigations into electrolytic chemistry.
The theory of electrolytic dissociation advanced by Ostwald shows that
the molecules of electrolytes in aqueous solutions are broken down into
electrically charged parts called ions. In very dilute solutions the
dissociation of strong acids, bases, and salts is practically complete
as was suggested by Williamson in 1851.
Catalysis, or reaction brought about by agents which do not enter into
the chemical changes, was discovered by Berzelius. Ostwald investigated
and developed catalytic reactions which are now extensively employed
in industry, particularly in refining oils and in the fixation of
nitrogen. Hot platinum, for example, is used to act catalytically in
causing sulphur dioxide and oxygen to combine and form the basis of
sulphuric acid, sulphur trioxide.
One of the most important applications of catalysis to industry is the
Haber process for securing nitrogen from the air. When air and hydrogen
are compressed and heated to a high temperature in the presence of a
catalyzer such as metallic uranium or iron carbide, the nitrogen and
hydrogen combine and form ammonia.
The experiments of Sir William Crookes on vacuum tubes subjected to
electrical impulses led the way to the discovery of radioactivity, and
investigations of radium have revolutionized our conceptions of the
nature and properties of matter.
The discovery of helium, argon, the niton emanation from radium and
other elements by Ramsay, Collie, Soddy, and others will be referred to
later.
Carl Linnæus, who is called the father of modern botany, established
the genera and species of plants upon philosophical principles. He
established a binomial nomenclature and formulated modern descriptive
methods. Thus he prepared the way for the systematic works of De
Jussieu and De Candolle.
De Candolle, in 1819, published a new method of classification based
upon morphological characters. He defined and illustrated the
doctrine of the symmetry of plant organs and asserted that a natural
classification must be based on a plan of symmetry.
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