Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
Every chemical student to-day is told that the elementary nature of
chlorine was first _demonstrated_ by Davy, and if the student is
informed what Davy meant by the term “element,” the statement is not
incorrect. What, however, Davy actually did was to demonstrate that
the substance called oxymuriatic acid contained no oxygen; that it was
a peculiar substance which “has not as yet been decompounded,” and
therefore is “elementary as far as our knowledge extends.” The very
character of the name which he suggested indicates this cautious and
philosophical view. In making the suggestion, he says:--
“To call a body which is not known to contain oxygen and which
cannot contain muriatic acid, oxymuriatic acid, is contrary to
the principles of that nomenclature in which it is adopted;
and an alteration of it seems necessary to assist the progress
of discussion, and to diffuse just ideas on the subject. If the
great discoverer of this substance [Scheele, who first observed
it in 1774] had signified it by any simple name, it would have
been proper to have recurred to it; but, _dephlogisticated marine
acid_ is a term which can hardly be adopted in the present
advanced era of the science.
“After consulting some of the most eminent chemical philosophers
in this country, it has been judged most proper to suggest
a name founded upon one of its obvious and characteristic
properties--its colour, and to call it _chlorine_, or _chloric_
gas.[H]
“Should it hereafter be discovered to be compound, and even
to contain oxygen, this name can imply no error, and cannot
necessarily require a change.”
[H] [From χλωρος.]
As the actual facts and arguments on which Davy based his views
are seldom set forth in text-books, or presented to the student by
teachers, it may be desirable to give a detailed account of his famous
memoir. He begins by saying:--
“The illustrious discoverer of the oxymuriatic acid considered
it as muriatic acid freed from hydrogen; and the common muriatic
acid as a compound of hydrogen and oxymuriatic acid; and on this
theory he denominated oxymuriatic acid dephlogisticated muriatic
acid.
“M. Berthollet, a few years after the discovery of Scheele, made
a number of important and curious experiments on this body; from
which he concluded that it was composed of muriatic acid and
oxygen; and this idea for nearly twenty years has been almost
universally adopted.”
Public-domain text, read in full here on John Shaqi.
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