Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
In his fifth Bakerian lecture, “On some of the Combinations of
Oxymuriatic Gas and Oxygene, and on the chemical Relations of these
Principles to inflammable Bodies,” read before the Royal Society on
November 15th, 1810, he still further developed his ideas respecting
the nature of chlorine. Gay Lussac and Thenard, who had convinced
themselves that potassium and sodium are not hydrates of potash and
soda, had made known the fact that potassium can combine with oxygen
in more than one proportion; and Davy had confirmed their conclusion,
seeing in it a further proof of his views concerning the constitution
of the hyper-oxymuriate of potash. He then studied the behaviour of
a large number of the metals and their oxides with chlorine, making
in many cases quantitative determinations, from which very fair
approximations to the combining proportions or atomic weights of the
substances may be deduced. Thus, he says “the number representing the
proportion in which mercury combines must be about 200,” and that “the
quantity of chlorine in corrosive sublimate is exactly double that in
calomel, and that the orange oxide contains twice as much oxygen as the
black, the mercury being considered the same in all.” The atomic weight
of silver deducible from the amount of chlorine taken up by that metal
during its conversion into horn-silver is almost exactly the value
obtained by the most rigorous analyses of modern times. It is, however,
noteworthy that in this paper Davy is brought into sharp conflict
with Dalton, and there is a characteristic exhibition of temper in
the way in which he protests against the manner in which Dalton had
sought to use certain of his numerical estimations in deducing the
weights of atoms. The comparative merits of Mr. Higgins and John
Dalton as the real authors of the explanation of the laws of chemical
combination have now been fully and finally assessed, but it was wholly
unnecessary for the purpose of Davy’s contention to underrate the
originality of the Manchester chemist. Dalton was no doubt wrong in the
assumption that 47 represented the weight of the atom of nitrogen, and
Davy was right in pointing out the invalidity of the basis on which
this assumption rested, and in his statement that 13·4 more nearly
represented the smallest proportion in which nitrogen is known to
combine. Davy says:--
“I shall enter no further at present into an examination of the
opinions, results, and conclusions of my learned friend; I am
however obliged to dissent from most of them, and to protest
against the interpretations that he has been pleased to make of
my experiments; and I trust to his judgment and candour for a
correction of his views.
Public-domain text, read in full here on John Shaqi.
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