Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“It ought not to interfere with truth and justice; but I will not
moralise nor complain. Iodine is as useful an ally to me as I
could have found at home.”
At Florence he worked in the laboratory of the Accademia del Cimento
on iodine and on the diamond. The results of his work on iodine he
embodied in a paper read to the Royal Society on June 16th, 1814, which
deals mainly with the iodates, or, as he preferred to call them, the
_oxyiodes_. The object of his work on the diamond was to determine
whether any peculiar matter separated from it during its combustion,
and whether the gas formed in the process was precisely the same in
its chemical nature as that produced by the combustion of plumbago and
charcoal. At Florence he made use of the great burning-glass originally
employed in the trials on the action of solar heat on the diamond
instituted by Cosmo III., Grand Duke of Tuscany; he completed the
research in the laboratory of the Accademia dei Lincei at Rome.
From the results of his different experiments, which were communicated
to the Royal Society on June 23rd, 1814, it appeared that the diamond
affords no other substance by its combustion in oxygen than pure
carbonic acid gas, and that the only chemical difference perceptible
between diamond and the purest charcoal is that the latter contains
a minute proportion of hydrogen. “But,” he asks, “can a quantity of
an element, less in some cases than 1/50000 part of the weight of the
substance, occasion so great a difference in physical and chemical
characters?” This he concludes is most unlikely, for, as he points out,
even when the minute quantity of hydrogen is expelled by heating the
charcoal in chlorine, the specific differences remain.
The doctrine at that time current, and which seemed indeed almost
axiomatic, “That bodies cannot be exactly the same in composition
or chemical nature, and yet totally different in all their physical
properties,” received its first great shock. Davy’s work, no doubt,
paved the way for the recognition of the fact of allotropy, and
thereafter of isomerism.
In May he went to Naples and made his first ascent of Vesuvius,
which he revisited on several subsequent journeys. He commissioned
one of the guides to inform him from time to time of the condition
of the volcano, and the man’s letters, in spite of their phonetic
address--“Siromfredevi-Londra”--duly found their way to Albemarle
Street. He also interested himself in the excavations at Pompeii
instituted by direction of Murat, then King of Naples, and he performed
a number of experiments on the colours used by the ancients in
painting, an account of which was communicated to the Royal Society on
February 23rd, 1815.
He then passed northwards with the intention of spending the summer at
Geneva. On his way he called at Milan to pay his respects to Volta. Of
this visit he wrote:--
Public-domain text, read in full here on John Shaqi.
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