Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“In reflecting on the circumstances of the two species of
combustion I was led to imagine that the cause of the superiority
of the light of the _stream_ of coal gas might be owing to the
_decomposition_ of a part of the gas towards the interior of the
flame, where the air was in smallest quantity, and the deposition
of solid charcoal, which, first by its _ignition_, and afterwards
by its combustion, increased in a high degree the intensity of
the light.”
The principle of the increase of the brilliancy and density of flame
by the production and ignition of solid matter explains the appearance
of the different parts of the flames of burning bodies, and of the
blow-pipe flame; it also explains the intensity of the light of those
flames in which fixed solid matter is produced in combustion, _e.g._
phosphorus and zinc in oxygen, potassium in chlorine; and, on the
other hand, the feebleness of the light of flames in which gaseous
and volatile matter is alone produced, _e.g._ hydrogen in oxygen,
phosphorus in chlorine. Davy’s theory has not been unchallenged, but
all subsequent research, when pushed sufficiently far, has shown that,
as regards all ordinary illuminating flames, _i.e._ carbonaceous
flames--_e.g._ coal-gas, oil, paraffin, candle--the presence of solid
incandescent carbon is a prime cause of their luminosity. It had
been observed that the rarefaction of a mixture of inflammable gases
diminishes its combustibility: Davy proved that this diminution was
not the result of the removal of pressure _per se_, but of the cooling
effect thus indirectly produced. Hence, the lower the temperature of
ignition of a gaseous mixture the more it may be rarefied without
becoming uninflammable. In like manner he shows that by heating the
gaseous mixture it may be caused to explode at a lower temperature,
and that when gases combine by sudden compression, the combination is
caused by the heat evolved. Also that the power of an indifferent gas
to prevent the explosion of a gaseous mixture depends upon its power
of abstracting heat, and that the higher the temperature of ignition
of the explosive mixture the less is the amount of indifferent gas
required to stop the explosion. He proved that it was quite possible
to effect the gradual combination of gases without flame--that is,
without the production of heat sufficient to raise the products to
incandescence; and he discovered the singular fact that platinum would
induce the combination of many inflammable gases and vapours, and on
this circumstance based the construction of his flameless lamp.
* * * * *
In the early summer of 1818, he thus wrote to his mother:--
Public-domain text, read in full here on John Shaqi.
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