Hygiene: a manual of personal and public health (New Edition)Newsholme, Arthur, Sir
Science
Hygiene: a manual of personal and public health (New Edition)
Newsholme, Arthur, Sir
Hygiene; Public health -- Great Britain; Sanitation
=Lead= is an occasional contamination of slightly acid waters. The
purest and most oxygenated waters act most readily on lead; as
also those containing organic matter, nitrates or nitrites. Waters
containing chlorides also act on lead, the chloride of lead being
sufficiently soluble to produce poisonous symptoms. Upland surface
waters derived from moorlands in certain districts, _e.g._ around
Sheffield, have been found to be capable of dissolving considerable
lead from lead service-pipes. The water taken first from the tap in
the early morning is the most heavily charged with lead. Such waters
are very soft; but other moorland soft waters do not dissolve lead.
It is the water having a slightly acid reaction which possesses this
property. The source of this acid, whether sulphuric acid from the
products of combustion in a neighbouring town, or an organic acid,
is uncertain. The plumbo-solvent action of such water is greatest in
autumn, when the amount of acid is at its maximum. The property of
dissolving lead is removed by passing the water on a large scale over
filters of sand, spongy iron, chalk, or limestone. The addition of
a small quantity of carbonate of soda has the same effect. In such
districts the use of tin-lined iron pipes for domestic services has
been recommended, but these are liable to fracture when bent. Pipes
consisting of an outer case of lead and an inner pipe of tin with a
layers of asbestos between have also been placed on the market. (See
also page 68.)
Hard waters have the least action on lead; a coating of insoluble
carbonate of lead being formed on the interior of the pipe, which
prevents any further action. Thus the use of lead pipes for water
containing carbonates or sulphate, or calcium phosphate, is
comparatively safe. Hard water containing carbonic acid gas under
pressure will dissolve a small amount of carbonate of lead; this
explains the cases of lead poisoning from soda water which was formerly
supplied in syphon bottles with lead tubes.
Lead is dissolved much more easily by water if other metals are in
contact with it, as iron, zinc, or tin, galvanic action being thus set
up. Zinc pipes containing some lead are very dangerous, especially with
the distilled water used on board ships.
=To determine the presence of lead in water=, place a given quantity,
say 100 c.c. in a white dish, and stir with a rod dipped in a solution
of ammonium sulphide; if the water becomes coloured, this is generally
due to the presence of iron or lead. If the colour remains after
adding a drop or two of hydrochloric acid, lead is present.
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