Illustrations of the Croton AqueductTower, F. B. (Fayette Bartholomew)
History
Illustrations of the Croton Aqueduct
Tower, F. B. (Fayette Bartholomew)
Croton Aqueduct (N.Y.)
These combinations, in the small quantities in which they exist, in no
degree injure the diluent properties of rain water. It is indeed to
the presence of the two elastic gases, that rain water owes the taste
which renders it palatable to animals and useful to vegetables. Ice
water, being destitute of these gases is extremely vapid; fish cannot
live in it; and it does not seem either to quench thirst or to be so
complete a solvent in the stomach as rain water. Carbonate of ammonia
is also another ingredient. It is derived from the putrefaction of
nitrogenous substances. When several hundred pounds of rain water were
distilled by Liebig, in a copper still, and the first two or three
pounds evaporated with the addition of a little muriatic acid, he
found a very distinct crystallization of sal-ammoniac, the crystals
having a brown or yellow color. “It is worthy of observation,” says
Liebig, “that the ammonia contained in rain and snow water possesses
an offensive smell of perspiration and animal excrements, a fact which
leaves no doubt respecting its origin.” It is owing to the presence of
carbonate of ammonia that rain water owes its _softer_ feel than pure
distilled water. According to Liebig, it is the atmospheric ammonia
which furnishes the nitrogen of plants. The traces of nitric acid which
have been detected in the air, are referable to the oxidation of the
constituents of ammonia; and not to the direct union of the oxygen and
free nitrogen of the atmosphere. Dr. Pereira states that a carbonaceous
(sooty) substance, and traces of sulphates, chlorides, and calcareous
matter, are the usual impurities of the first rain water of a shower.
Zimmerman found oxide of iron and chloride potassium in rain water;
other chemists have been able to detect no iron in it, but have found
meteoric iron and nickel in dew. Brande detected in it, chloride of
sodium, chloride of magnesium, sulphate and carbonate of magnesium,
sulphate of lime, and oxide of manganese. The putrefaction to which
rain water is subject, shows that some organic matter is present. The
term _pyrrhin_ (from πυρρος red) has been applied by Zimmerman to
an atmospheric organic substance which reddens solutions of silver.
Whenever rain water is collected near large towns, it should be boiled
and strained before use, as it contains less saline impregnation than
other kinds of natural waters, it is more apt to become contaminated
with lead from roofs, gutters, cisterns, and water pipes. To purify
rain water and render it useful, for the delicate purposes of chemical
experiment, Morveau recommends dropping into it a little barytic
water and then exposing it for some time to the atmospheric air.
This combines with the carbonic acid, which being the solvent of the
carbonate of lime, both it and the carbonate of baryta are precipitated
as insoluble salts. Instead of exposing it to the atmosphere, it may be
poured from one vessel to another; by which means not only the minute
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