Illustrations of the Croton AqueductTower, F. B. (Fayette Bartholomew)
History
Illustrations of the Croton Aqueduct
Tower, F. B. (Fayette Bartholomew)
Croton Aqueduct (N.Y.)
Christison has proved that the lead
which is dissolved, is in the form of the carbonate, and hydrate of the
oxide, or, oxide of lead, carbonic acid and water.
The fact is then sufficiently established, that distilled water has
the property of dissolving lead--Does the same hold true in relation
to waters in ordinary use? In the year 1809, it was first announced by
_Guyton Morveau_, that the salts which are held in solution by some
natural waters, destroy their property of acting on lead, and that of
these modifying circumstances none are more remarkable in their action
than the neutral salts. Dr. Christison has pursued this investigation
with great success, and has proved that this preservative power
exists in the case of sulphates, muriates, carbonates, hydriodates,
phosphates, nitrates, acetates, tartrates, arseniates, &c. These
salts, however, do not possess an equally protective influence, the
carbonates and sulphates being most, the chlorides the least energetic
of those saline substances commonly met with in waters. As a general
rule, it appears that those whose acid forms with the lead a soluble
salt of lead, are the least energetic; while those whose acid forms an
insoluble salt of lead, are most energetic. The variable quantity of
salts necessary to prevent the action of water on lead, may be seen
from the following results obtained by actual experiment.
Of acetate of soda a 100th part of the water is a preservative.
Of arseniate of soda 12,000th „ „ „
Of phosphate of soda 30,000th „ „ „
Of hydriodate of potash 30,000th „ „ „
Of muriate of soda 2,000th „ „ „
Of sulphate of lime 4,000th „ „ „
Of nitrate of potash 100th „ „ „
The sulphates of soda, magnesia, lime, and the triple sulphate of
alumina and potash, possess about the same preservative power; which
appears to depend on the acid, not on the base of the salt. The general
results of Dr. Christison’s investigations, appear to be, that neutral
salts in various, and for the most part minute, proportions, retard or
prevent the corrosive action of water on lead--allowing the carbonate
to deposit itself slowly, and to adhere with such firmness to the
lead as not to be afterwards removed by moderate agitation,--adding
subsequently to this crust other insoluble salts of lead, the acids
of which are derived from the neutral salts in solution,--and thus at
length forming a permanent and impermeable screen in the form of a
film over its surface, through which the action of the water cannot
any longer be carried on. These films are composed of the carbonate of
lead, with a little of the muriate, sulphate, arseniate, or phosphate
of lead, according to the nature of the acid in the alkaline salt,
which is dissolved in the water. The following general conclusions may
therefore be considered as sufficiently established.
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