Grinding of _ultramarine_ and _alum_ requires to be done in closed-in
mills, and any dust drawn away by locally applied ventilation and
filtered. The gases given off in the burning process contain 3 per cent.
of sulphur dioxide, which requires to be absorbed—a procedure most easily
effected in towers where the upstreaming gas comes into contact with a
dilute solution of lime or soda.
Chlorine, Bleaching Powder, Chlorine Compounds
(See also pp. 23-9 and 173)
What has been said as to imperviousness of apparatus, negative pressure
maintained by the tall chimney stack or earthenware or fireclay fan,
&c., applies equally here. The exhaust ventilation is also required to
aspirate the gas into the bleaching chambers.
At the end of the system there must be either a tower packed with
quicklime to absorb the last traces of chlorine or such a number of
bleach chambers into which the gas can be led that no chlorine escapes.
Production of chlorine gas electrolytically is to be preferred to other
processes on hygienic grounds.
Careful cleanliness is the best prophylactic against occurrence of
_chlorine rash_ among persons employed in the electrolytic production of
chlorine. In some factories attempt has been made to use other substances
(magnetite) instead of carbon for the anode, and the success attending
their adoption is further proof that the tar cement at the anode helped
to cause the acne.
In the _Weldon_ process care must be taken that the water lutes are
intact, and the stills must not be opened before the chlorine has been
drawn off. All processes in which manganese dust can arise (grinding
of manganese dioxide and drying of Weldon deposit) should be done
under locally applied exhaust. The _bleaching powder_ chambers must be
impervious and care taken that they are not entered before the chlorine
has been absorbed. Usually the number of lime chambers connected up with
each other is such that no chlorine escapes free into the air. Emptying
of the finished product should not be done by hand, as considerable
quantities of chlorine escape and make the work extremely irksome.
Mechanical methods of emptying should be adopted in substitution for hand
labour, and of these the Hasenclever closed-in apparatus is the best.
Nitric Acid and Explosives
(See also pp. 39-49 and 172)
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