Dangerous acid fumes (notably nitrous fumes) are evolved in metal
pickling, especially of brass articles (such as harness furniture,
lamp fittings, church utensils, &c.), for the purpose of giving them a
shiny or dull surface by immersion in baths of nitric, hydrochloric, or
sulphuric acid. As severe and even fatal poisoning has occurred in these
operations they should be conducted in isolated compartments or channels
under exhaust ventilation. If the ventilation provided is mechanical an
acid proof earthenware fan or an injector is necessary. The following
description applies to one large works: The pickling troughs are placed
in a wooden compartment closed in except for a small opening in front.
To this compartment a stoneware pipe leading to a stoneware fan is
connected. The nitrous fumes are drawn through the pipe and led into
the lower part of an absorption tower filled with cone-shaped packing
material through which water trickles from a vessel placed at the top.
The greater part of the acid fumes are absorbed as they pass upwards
and the water collects in a receiver below, from which it is blown by
compressed air into the vessel above for utilisation again until it
becomes so charged with acid that it can be used for pickling purposes.
In _galvanising_ and _tinning_ acid fumes, injurious acroleic vapour, and
metallic fumes can arise as the metal articles (iron, copper, &c.) first
require to be cleaned in an acid bath and then dipped into molten fat
or molten zinc or tin. Here also the fumes should be drawn away in the
manner described.
Recovery and Use of Mercury
Escape of mercury vapour and development of sulphur dioxide seriously
endanger workers engaged in smelting cinnabar. The danger can be
minimised by proper construction of furnaces preventing escape as far
as possible of fumes and most careful condensation of the mercury in
impervious and sufficiently capacious chambers and flues.
Continuous furnaces are to be preferred to those working intermittently.
The system of condensing chambers and flues must offer as long a passage
as possible to the fumes, and care must be taken to keep them thoroughly
cool. Removal of the deposit rich in mercury from the flues is especially
fraught with danger. This work should only be carried on after efficient
watering by workers equipped with respirators, working suits, &c.
_Use of mercury._—Mirror making by coating the glass with mercury used
to be one of the most dangerous occupations. Now that a fully adequate
substitute for mercury has been found in the nitrate of silver and
ammonia process, use of mercury should be prohibited. As a home industry
especially mirror coating with mercury should be suppressed. Fortunately
the dangerous mode of production is rapidly being ousted.
The following requirements are contained in a decree of the Prussian
Government dated May 18, 1889:
(1) Medical certificate on admission to employment in mirror making with
use of mercury;
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